Fabrication of microstructures in III–V semiconductors by proton beam writing

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Title: Fabrication of microstructures in III–V semiconductors by proton beam writing
Authors: Menzel, F. fmenzel@physik.uni-leipzig.de, Spemann, D.1, Lenzner, J.1, Böhlmann, W.1, Zimmermann, G.1, Butz, T.1
Source: Nuclear Instruments & Methods in Physics Research Section B. Jun2009, Vol. 267 Issue 12/13, p2321-2326. 6p.
Subjects: Microfabrication, Semiconductor etching, Microstructure, Lithography, Proton beams, Gallium arsenide, Helium ions
Abstract: Abstract: While the creation of microstructures in Si and GaAs by irradiation with high energy protons and helium ions and subsequent electrochemical etching has already been reported, the creation of microstructures in InP using this technique is investigated here for the first time. It is demonstrated that proton irradiation of Fe-doped semi-insulating InP(001) leads to an amplified material removal in the irradiated areas during electrochemical etching in an HF solution. By this way microstructures were produced using a 2.25MeV proton beam focused down to ∼1μm. The depth of the etched structures depends on the etching procedure. In addition, amplified etching of non-irradiated material encircled by closed irradiated patterns was observed. Furthermore, irradiation with helium ions leads to the formation of thin freestanding InP layers by simultaneous underetching as well as etching from the sample surface of the irradiated regions. In contrast to the semi-insulating material, the irradiation and electrochemical etching of n-type InP results in an amplified formation of porous material which partly leads to a complete removal of the material in the irradiated areas. A comparison between GaAs and InP concerning the dissolution characteristics shows mainly a similar behavior of the semi-insulating types of these semiconductors and of the n-type materials. [Copyright &y& Elsevier]
Copyright of Nuclear Instruments & Methods in Physics Research Section B is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Fabrication of microstructures in III–V semiconductors by proton beam writing
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  Data: <searchLink fieldCode="AR" term="%22Menzel%2C+F%2E%22">Menzel, F.</searchLink><i> fmenzel@physik.uni-leipzig.de</i><br /><searchLink fieldCode="AR" term="%22Spemann%2C+D%2E%22">Spemann, D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lenzner%2C+J%2E%22">Lenzner, J.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Böhlmann%2C+W%2E%22">Böhlmann, W.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zimmermann%2C+G%2E%22">Zimmermann, G.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Butz%2C+T%2E%22">Butz, T.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Nuclear+Instruments+%26+Methods+in+Physics+Research+Section+B%22">Nuclear Instruments & Methods in Physics Research Section B</searchLink>. Jun2009, Vol. 267 Issue 12/13, p2321-2326. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Microfabrication%22">Microfabrication</searchLink><br /><searchLink fieldCode="DE" term="%22Semiconductor+etching%22">Semiconductor etching</searchLink><br /><searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br /><searchLink fieldCode="DE" term="%22Lithography%22">Lithography</searchLink><br /><searchLink fieldCode="DE" term="%22Proton+beams%22">Proton beams</searchLink><br /><searchLink fieldCode="DE" term="%22Gallium+arsenide%22">Gallium arsenide</searchLink><br /><searchLink fieldCode="DE" term="%22Helium+ions%22">Helium ions</searchLink>
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  Data: Abstract: While the creation of microstructures in Si and GaAs by irradiation with high energy protons and helium ions and subsequent electrochemical etching has already been reported, the creation of microstructures in InP using this technique is investigated here for the first time. It is demonstrated that proton irradiation of Fe-doped semi-insulating InP(001) leads to an amplified material removal in the irradiated areas during electrochemical etching in an HF solution. By this way microstructures were produced using a 2.25MeV proton beam focused down to ∼1μm. The depth of the etched structures depends on the etching procedure. In addition, amplified etching of non-irradiated material encircled by closed irradiated patterns was observed. Furthermore, irradiation with helium ions leads to the formation of thin freestanding InP layers by simultaneous underetching as well as etching from the sample surface of the irradiated regions. In contrast to the semi-insulating material, the irradiation and electrochemical etching of n-type InP results in an amplified formation of porous material which partly leads to a complete removal of the material in the irradiated areas. A comparison between GaAs and InP concerning the dissolution characteristics shows mainly a similar behavior of the semi-insulating types of these semiconductors and of the n-type materials. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Nuclear Instruments & Methods in Physics Research Section B is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.1016/j.nimb.2009.03.023
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Semiconductor etching
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      – SubjectFull: Microstructure
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      – SubjectFull: Lithography
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      – SubjectFull: Proton beams
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      – SubjectFull: Gallium arsenide
        Type: general
      – SubjectFull: Helium ions
        Type: general
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      – TitleFull: Fabrication of microstructures in III–V semiconductors by proton beam writing
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              Text: Jun2009
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