Characterization of interpenetrating networks of acrylic acid (AAc) and N-isopropylacrylamide (NIPAAm) synthesized by ionizing radiation

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Title: Characterization of interpenetrating networks of acrylic acid (AAc) and N-isopropylacrylamide (NIPAAm) synthesized by ionizing radiation
Authors: Adem, E.1, Burillo, G.2 burillo@nucleares.unam.mx, Bucio, E.2, Magaña, C.1, Avalos-Borja, M.3
Source: Radiation Physics & Chemistry. Jul2009, Vol. 78 Issue 7/8, p549-552. 4p.
Subjects: Polymer networks, Acrylic acid, Acrylamide, Organic synthesis, Ionizing radiation, Chemical reactions, Scanning electron microscopy, Crosslinking (Polymerization), Electron beams
Abstract: Abstract: Interpenetrating networks of poly(acrylic acid) (PAAc) and poly(N-isopropylacrylamide) (PNIPAAm) were synthesized in two consecutive steps utilizing ionizing radiation in the first step and chemical reaction in the second step. The first network of PAAc hydrogel was formed by ionizing radiation (gamma or electron beam). The secondary gel of PNIPAAm was synthesized directly within the primary gel of PAAc from an aqueous solution of N-isopropylacrylamide (NIPAAm) containing a crosslinking agent, accelerator and redox initiator. The interpenetrating networks (IPNs) were characterized morphologically by scanning electron microscopy (SEM), and their thermal behavior was analyzed by differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). [Copyright &y& Elsevier]
Copyright of Radiation Physics & Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 42104027
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Characterization of interpenetrating networks of acrylic acid (AAc) and N-isopropylacrylamide (NIPAAm) synthesized by ionizing radiation
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  Data: <searchLink fieldCode="AR" term="%22Adem%2C+E%2E%22">Adem, E.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Burillo%2C+G%2E%22">Burillo, G.</searchLink><relatesTo>2</relatesTo><i> burillo@nucleares.unam.mx</i><br /><searchLink fieldCode="AR" term="%22Bucio%2C+E%2E%22">Bucio, E.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Magaña%2C+C%2E%22">Magaña, C.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Avalos-Borja%2C+M%2E%22">Avalos-Borja, M.</searchLink><relatesTo>3</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Radiation+Physics+%26+Chemistry%22">Radiation Physics & Chemistry</searchLink>. Jul2009, Vol. 78 Issue 7/8, p549-552. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Polymer+networks%22">Polymer networks</searchLink><br /><searchLink fieldCode="DE" term="%22Acrylic+acid%22">Acrylic acid</searchLink><br /><searchLink fieldCode="DE" term="%22Acrylamide%22">Acrylamide</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+synthesis%22">Organic synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Ionizing+radiation%22">Ionizing radiation</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopy%22">Scanning electron microscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Crosslinking+%28Polymerization%29%22">Crosslinking (Polymerization)</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+beams%22">Electron beams</searchLink>
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  Data: Abstract: Interpenetrating networks of poly(acrylic acid) (PAAc) and poly(N-isopropylacrylamide) (PNIPAAm) were synthesized in two consecutive steps utilizing ionizing radiation in the first step and chemical reaction in the second step. The first network of PAAc hydrogel was formed by ionizing radiation (gamma or electron beam). The secondary gel of PNIPAAm was synthesized directly within the primary gel of PAAc from an aqueous solution of N-isopropylacrylamide (NIPAAm) containing a crosslinking agent, accelerator and redox initiator. The interpenetrating networks (IPNs) were characterized morphologically by scanning electron microscopy (SEM), and their thermal behavior was analyzed by differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Radiation Physics & Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.radphyschem.2009.03.040
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        Text: English
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        StartPage: 549
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      – SubjectFull: Acrylic acid
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      – SubjectFull: Acrylamide
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      – SubjectFull: Chemical reactions
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      – SubjectFull: Scanning electron microscopy
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      – SubjectFull: Crosslinking (Polymerization)
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      – SubjectFull: Electron beams
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      – TitleFull: Characterization of interpenetrating networks of acrylic acid (AAc) and N-isopropylacrylamide (NIPAAm) synthesized by ionizing radiation
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              Text: Jul2009
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              Y: 2009
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