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Beyond holo/hemidirectionality in Pb(II) complexes: Can the valence lone pair be bisdirected?

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Title: Beyond holo/hemidirectionality in Pb(II) complexes: Can the valence lone pair be bisdirected?
Authors: Severen, M.-C. van, Piquemal, J.-P. jpp@lct.jussieu.fr, Parisel, O. parisel@lct.jussieu.fr
Source: Chemical Physics Letters. Aug2009, Vol. 478 Issue 1-3, p17-19. 3p.
Subjects: Metal complexes, Lead compounds, Density functionals, Conduction electrons, Localization theory
Abstract: Abstract: In this contribution, we investigate, by means of Density Functional Theory computations coupled to the analysis of the Electron Localisation Function (ELF), a new possible topology of the Pb2+ valence lone pair. The possibility of bisdirectionality is uncovered for the first time and reveals another character of lead complexes beyond holo/hemidirectionality. [Copyright &y& Elsevier]
Copyright of Chemical Physics Letters is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 43617966
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Beyond holo/hemidirectionality in Pb(II) complexes: Can the valence lone pair be bisdirected?
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  Data: <searchLink fieldCode="AR" term="%22Severen%2C+M%2E-C%2E+van%22">Severen, M.-C. van</searchLink><br /><searchLink fieldCode="AR" term="%22Piquemal%2C+J%2E-P%2E%22">Piquemal, J.-P.</searchLink><i> jpp@lct.jussieu.fr</i><br /><searchLink fieldCode="AR" term="%22Parisel%2C+O%2E%22">Parisel, O.</searchLink><i> parisel@lct.jussieu.fr</i>
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  Data: <searchLink fieldCode="JN" term="%22Chemical+Physics+Letters%22">Chemical Physics Letters</searchLink>. Aug2009, Vol. 478 Issue 1-3, p17-19. 3p.
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  Data: <searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Lead+compounds%22">Lead compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Density+functionals%22">Density functionals</searchLink><br /><searchLink fieldCode="DE" term="%22Conduction+electrons%22">Conduction electrons</searchLink><br /><searchLink fieldCode="DE" term="%22Localization+theory%22">Localization theory</searchLink>
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  Label: Abstract
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  Data: Abstract: In this contribution, we investigate, by means of Density Functional Theory computations coupled to the analysis of the Electron Localisation Function (ELF), a new possible topology of the Pb2+ valence lone pair. The possibility of bisdirectionality is uncovered for the first time and reveals another character of lead complexes beyond holo/hemidirectionality. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Chemical Physics Letters is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.cplett.2009.07.036
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        Text: English
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      – SubjectFull: Lead compounds
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      – SubjectFull: Density functionals
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      – SubjectFull: Conduction electrons
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      – SubjectFull: Localization theory
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      – TitleFull: Beyond holo/hemidirectionality in Pb(II) complexes: Can the valence lone pair be bisdirected?
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              Text: Aug2009
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