Penetration depth and transient oxidation of graphite by oxygen and water vapor

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Title: Penetration depth and transient oxidation of graphite by oxygen and water vapor
Authors: Wichner, Robert P.1 wichner@bellsouth.net, Burchell, Timothy D.2, Contescu, Cristian I.2 contescuci@ornl.gov
Source: Journal of Nuclear Materials. Sep2009, Vol. 393 Issue 3, p518-521. 4p.
Subjects: Chemical kinetics, Oxidation, Graphite, Estimates, Temperature effect, Atmospheric water vapor, Chemical equilibrium
Abstract: Abstract: Equations are derived for the approach to equilibrium in the oxidation of graphite under assumptions of constant graphite density and linearized oxidation kinetics. A two-factor expression is assumed for the effective diffusivity. Equilibration may be estimated by observing the convergence of profiles with time or by means of an algebraic approximation. At large times, the profiles converge to the steady state. Oxidation depths show fair agreement with published measurements and follow closely the observed temperature trend. [Copyright &y& Elsevier]
Copyright of Journal of Nuclear Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 44108645
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Penetration depth and transient oxidation of graphite by oxygen and water vapor
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  Data: <searchLink fieldCode="AR" term="%22Wichner%2C+Robert+P%2E%22">Wichner, Robert P.</searchLink><relatesTo>1</relatesTo><i> wichner@bellsouth.net</i><br /><searchLink fieldCode="AR" term="%22Burchell%2C+Timothy+D%2E%22">Burchell, Timothy D.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Contescu%2C+Cristian+I%2E%22">Contescu, Cristian I.</searchLink><relatesTo>2</relatesTo><i> contescuci@ornl.gov</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Nuclear+Materials%22">Journal of Nuclear Materials</searchLink>. Sep2009, Vol. 393 Issue 3, p518-521. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Chemical+kinetics%22">Chemical kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation%22">Oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Graphite%22">Graphite</searchLink><br /><searchLink fieldCode="DE" term="%22Estimates%22">Estimates</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature+effect%22">Temperature effect</searchLink><br /><searchLink fieldCode="DE" term="%22Atmospheric+water+vapor%22">Atmospheric water vapor</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+equilibrium%22">Chemical equilibrium</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Equations are derived for the approach to equilibrium in the oxidation of graphite under assumptions of constant graphite density and linearized oxidation kinetics. A two-factor expression is assumed for the effective diffusivity. Equilibration may be estimated by observing the convergence of profiles with time or by means of an algebraic approximation. At large times, the profiles converge to the steady state. Oxidation depths show fair agreement with published measurements and follow closely the observed temperature trend. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Nuclear Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1016/j.jnucmat.2009.06.032
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      – Code: eng
        Text: English
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        PageCount: 4
        StartPage: 518
    Subjects:
      – SubjectFull: Chemical kinetics
        Type: general
      – SubjectFull: Oxidation
        Type: general
      – SubjectFull: Graphite
        Type: general
      – SubjectFull: Estimates
        Type: general
      – SubjectFull: Temperature effect
        Type: general
      – SubjectFull: Atmospheric water vapor
        Type: general
      – SubjectFull: Chemical equilibrium
        Type: general
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      – TitleFull: Penetration depth and transient oxidation of graphite by oxygen and water vapor
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              M: 09
              Text: Sep2009
              Type: published
              Y: 2009
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              Value: 393
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