Bibliographic Details
| Title: |
A new synthetic route towards a Ru(III) substituted heteropolytungstate anion |
| Authors: |
Besson, Claire1, Chen, Su-Wen1, Villanneau, Richard1, Izzet, Guillaume guillaume.izzet@upmc.fr, Proust, Anna |
| Source: |
Inorganic Chemistry Communications. Oct2009, Vol. 12 Issue 10, p1042-1044. 3p. |
| Subjects: |
Ruthenium compounds, Polytungstates, Complex compounds synthesis, Microwaves, Irradiation, Ammonium salts, X-ray absorption near edge structure, Electron paramagnetic resonance spectroscopy |
| Abstract: |
Abstract: Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4− anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates. [Copyright &y& Elsevier] |
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| Database: |
Engineering Source |
