Bibliographic Details
| Title: |
Selective Oxidation of sp3C−H Bonds in Water Catalyzed by a Glycinate−Platinum(II) Complex. |
| Authors: |
George S. Chen1, Jay A. Labinger1, John E. Bercaw1 |
| Source: |
Organometallics. Sep2009, Vol. 28 Issue 17, p4899-4901. 3p. |
| Subjects: |
Metal complexes, Organoplatinum compounds, Chemical bonds, Oxidation, Water, Solution (Chemistry), Methyl groups, Sulfonates |
| Abstract: |
In aqueous solution, [PtII(glycinato)Cl2]−catalyzes oxidation by [PtIVCl6]2−of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [PtIICln(H2O)4−n]2−nas the catalyst. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
