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Selective Oxidation of sp3C−H Bonds in Water Catalyzed by a Glycinate−Platinum(II) Complex.

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Title: Selective Oxidation of sp3C−H Bonds in Water Catalyzed by a Glycinate−Platinum(II) Complex.
Authors: George S. Chen1, Jay A. Labinger1, John E. Bercaw1
Source: Organometallics. Sep2009, Vol. 28 Issue 17, p4899-4901. 3p.
Subjects: Metal complexes, Organoplatinum compounds, Chemical bonds, Oxidation, Water, Solution (Chemistry), Methyl groups, Sulfonates
Abstract: In aqueous solution, [PtII(glycinato)Cl2]−catalyzes oxidation by [PtIVCl6]2−of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [PtIICln(H2O)4−n]2−nas the catalyst. [ABSTRACT FROM AUTHOR]
Copyright of Organometallics is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
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PubType: Academic Journal
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  Data: In aqueous solution, [PtII(glycinato)Cl2]−catalyzes oxidation by [PtIVCl6]2−of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [PtIICln(H2O)4−n]2−nas the catalyst. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Organometallics is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1021/om900267w
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      – Code: eng
        Text: English
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        PageCount: 3
        StartPage: 4899
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      – SubjectFull: Metal complexes
        Type: general
      – SubjectFull: Organoplatinum compounds
        Type: general
      – SubjectFull: Chemical bonds
        Type: general
      – SubjectFull: Oxidation
        Type: general
      – SubjectFull: Water
        Type: general
      – SubjectFull: Solution (Chemistry)
        Type: general
      – SubjectFull: Methyl groups
        Type: general
      – SubjectFull: Sulfonates
        Type: general
    Titles:
      – TitleFull: Selective Oxidation of sp3C−H Bonds in Water Catalyzed by a Glycinate−Platinum(II) Complex.
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            NameFull: George S. Chen
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              M: 09
              Text: Sep2009
              Type: published
              Y: 2009
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              Value: 28
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