XPS and IPE analysis of HfO2 band alignment with high-mobility semiconductors

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Bibliographic Details
Title: XPS and IPE analysis of HfO2 band alignment with high-mobility semiconductors
Authors: Perego, M.1 michele.perego@mdm.infm.it, Seguini, G.1, Fanciulli, M.1,2
Source: Materials Science in Semiconductor Processing. Oct2008, Vol. 11 Issue 5/6, p221-225. 5p.
Subjects: X-ray photoelectron spectroscopy, Epitaxy, Photoemission, Photoconductivity, Hafnium oxide, Gallium arsenide, Germanium
Abstract: Abstract: A detailed analysis of the band alignment between atomic-layer deposition (ALD)-grown HfO2 thin films and n-type Ge(100) substrate is presented. The valence band offset (VBO) is determined by X-ray photoelectron spectroscopy (XPS) after careful evaluation of the experimental data and accurate removal of the artefacts induced by differential charging phenomena occurring during XPS measurement. VBO values are 2.7±0.1eV for all samples independent of the different growth conditions. A conduction band offset (CBO) of 2.0±0.1eV and a band gap of 5.6±0.1eV have been obtained by internal photoemission (IPE) and photoconductivity measurements, respectively. VBO and CBO values obtained by the different techniques are in excellent agreement within the experimental error. [Copyright &y& Elsevier]
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Abstract:Abstract: A detailed analysis of the band alignment between atomic-layer deposition (ALD)-grown HfO2 thin films and n-type Ge(100) substrate is presented. The valence band offset (VBO) is determined by X-ray photoelectron spectroscopy (XPS) after careful evaluation of the experimental data and accurate removal of the artefacts induced by differential charging phenomena occurring during XPS measurement. VBO values are 2.7±0.1eV for all samples independent of the different growth conditions. A conduction band offset (CBO) of 2.0±0.1eV and a band gap of 5.6±0.1eV have been obtained by internal photoemission (IPE) and photoconductivity measurements, respectively. VBO and CBO values obtained by the different techniques are in excellent agreement within the experimental error. [Copyright &y& Elsevier]
ISSN:13698001
DOI:10.1016/j.mssp.2008.10.008