View in EDS

Characterization of High Phosphate Radioactive Tank Waste and Simulant Development.

Saved in:
Bibliographic Details
Title: Characterization of High Phosphate Radioactive Tank Waste and Simulant Development.
Authors: LUMETTA, GREGG J.1 gregg.lumetta@pnl.gov, MCNAMARA, BRUCE K.1, BUCK, EDGAR C.1, FISKUM, SANDRA K.1, SNOW, LANÉE A.1
Source: Environmental Science & Technology. 10/15/2009, Vol. 43 Issue 20, p7843-7848. 6p.
Subjects: Radioactive waste characterization, Plutonium industry, Radioactive waste disposal, Underground storage tanks, Hazardous waste site leaching, Hanford Site (Wash.), Savannah River Site (S.C.), Industry & the environment
Geographic Terms: Washington (State), South Carolina
Abstract: A sample at high-level radioactive tank waste was characterized to provide a basis for developing a waste simulant. The simulant is required for pilot-scale testing of pretreatment processes in a nonradiological facility. The waste material examined was derived from the bismuth phosphate process, which was the first industrial process implemented to separate plutonium from irradiated nuclear fuel. The bismuth phosphate process sludge is a complex mixture rich in bismuth, iron, sodium, phosphorus, silicon, and uranium. The form of phosphorus in this particular tank waste material in of specific importance because that is the primary component (other than water-soluble sodium salts) that must be removed from the high-level waste solids by pretreatment. This work shows unequivocally that the phosphorus in this waste material is not present as bismuth phosphate. Rather, the phosphorus appears to be incorporated mostly into an amorphous iron(III) phosphate phase. The bismuth in the sludge solids is best described as BiFeO3. The behavior of phosphorus during caustic leaching of the bismuth phosphate process sludge solids is also discussed. [ABSTRACT FROM AUTHOR]
Copyright of Environmental Science & Technology is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 45119689
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Characterization of High Phosphate Radioactive Tank Waste and Simulant Development.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22LUMETTA%2C+GREGG+J%2E%22">LUMETTA, GREGG J.</searchLink><relatesTo>1</relatesTo><i> gregg.lumetta@pnl.gov</i><br /><searchLink fieldCode="AR" term="%22MCNAMARA%2C+BRUCE+K%2E%22">MCNAMARA, BRUCE K.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22BUCK%2C+EDGAR+C%2E%22">BUCK, EDGAR C.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22FISKUM%2C+SANDRA+K%2E%22">FISKUM, SANDRA K.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22SNOW%2C+LANÉE+A%2E%22">SNOW, LANÉE A.</searchLink><relatesTo>1</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Environmental+Science+%26+Technology%22">Environmental Science & Technology</searchLink>. 10/15/2009, Vol. 43 Issue 20, p7843-7848. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Radioactive+waste+characterization%22">Radioactive waste characterization</searchLink><br /><searchLink fieldCode="DE" term="%22Plutonium+industry%22">Plutonium industry</searchLink><br /><searchLink fieldCode="DE" term="%22Radioactive+waste+disposal%22">Radioactive waste disposal</searchLink><br /><searchLink fieldCode="DE" term="%22Underground+storage+tanks%22">Underground storage tanks</searchLink><br /><searchLink fieldCode="DE" term="%22Hazardous+waste+site+leaching%22">Hazardous waste site leaching</searchLink><br /><searchLink fieldCode="DE" term="%22Hanford+Site+%28Wash%2E%29%22">Hanford Site (Wash.)</searchLink><br /><searchLink fieldCode="DE" term="%22Savannah+River+Site+%28S%2EC%2E%29%22">Savannah River Site (S.C.)</searchLink><br /><searchLink fieldCode="DE" term="%22Industry+%26+the+environment%22">Industry & the environment</searchLink>
– Name: SubjectGeographic
  Label: Geographic Terms
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Washington+%28State%29%22">Washington (State)</searchLink><br /><searchLink fieldCode="DE" term="%22South+Carolina%22">South Carolina</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A sample at high-level radioactive tank waste was characterized to provide a basis for developing a waste simulant. The simulant is required for pilot-scale testing of pretreatment processes in a nonradiological facility. The waste material examined was derived from the bismuth phosphate process, which was the first industrial process implemented to separate plutonium from irradiated nuclear fuel. The bismuth phosphate process sludge is a complex mixture rich in bismuth, iron, sodium, phosphorus, silicon, and uranium. The form of phosphorus in this particular tank waste material in of specific importance because that is the primary component (other than water-soluble sodium salts) that must be removed from the high-level waste solids by pretreatment. This work shows unequivocally that the phosphorus in this waste material is not present as bismuth phosphate. Rather, the phosphorus appears to be incorporated mostly into an amorphous iron(III) phosphate phase. The bismuth in the sludge solids is best described as BiFeO3. The behavior of phosphorus during caustic leaching of the bismuth phosphate process sludge solids is also discussed. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Environmental Science & Technology is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=45119689
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1021/es9013745
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 7843
    Subjects:
      – SubjectFull: Radioactive waste characterization
        Type: general
      – SubjectFull: Plutonium industry
        Type: general
      – SubjectFull: Radioactive waste disposal
        Type: general
      – SubjectFull: Underground storage tanks
        Type: general
      – SubjectFull: Hazardous waste site leaching
        Type: general
      – SubjectFull: Hanford Site (Wash.)
        Type: general
      – SubjectFull: Savannah River Site (S.C.)
        Type: general
      – SubjectFull: Industry & the environment
        Type: general
      – SubjectFull: Washington (State)
        Type: general
      – SubjectFull: South Carolina
        Type: general
    Titles:
      – TitleFull: Characterization of High Phosphate Radioactive Tank Waste and Simulant Development.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: LUMETTA, GREGG J.
      – PersonEntity:
          Name:
            NameFull: MCNAMARA, BRUCE K.
      – PersonEntity:
          Name:
            NameFull: BUCK, EDGAR C.
      – PersonEntity:
          Name:
            NameFull: FISKUM, SANDRA K.
      – PersonEntity:
          Name:
            NameFull: SNOW, LANÉE A.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 15
              M: 10
              Text: 10/15/2009
              Type: published
              Y: 2009
          Identifiers:
            – Type: issn-print
              Value: 0013936X
          Numbering:
            – Type: volume
              Value: 43
            – Type: issue
              Value: 20
          Titles:
            – TitleFull: Environmental Science & Technology
              Type: main
ResultId 1