A structural investigation of the coordination behaviour of 4,6-dimethylpyrimidine-2-thiol with Zinc (II) at pH 6 – A zwitterionic complex exhibiting unusual ZnS3N2 chromophore in solid state
Saved in:
| Title: | A structural investigation of the coordination behaviour of 4,6-dimethylpyrimidine-2-thiol with Zinc (II) at pH 6 – A zwitterionic complex exhibiting unusual ZnS |
|---|---|
| Authors: | Das, A.K.1 asishkdas2009@rediffmail.com, Gowda, N.S.2, Botoshansky, M.3, Sridhar, M.A.2, Kaftory, M.3, Prasad, J. Sashidhara2 |
| Source: | Journal of Molecular Structure. Dec2009, Vol. 938 Issue 1-3, p259-262. 4p. |
| Subjects: | Molecular structure, Pyrimidines, Organozinc compounds, Metal complexes, Hydrogen-ion concentration, Solid state chemistry, Zinc sulfate, Ligands (Chemistry) |
| Abstract: | Abstract: Complexation between Zn2+ and 4,6-dimethylpyrimidine-2-thiol was attempted with ZnO, ZnSO4 and Zn(OAc)2. In all cases, the same compound, tris-4,6-dimethylpyrimidine-2-thiolato zinc (II) was generated without anion incorporation. It crystallized from methanol in the space group P21/a, Z =4. The molecular structure exemplifies an uncommon coordination of 3 ligands to Zn(II) through their thiolate centres; one of the ligands is protonated to effectively form a zwitterionic complex, which exhibits capped rectangular pyramidal coordination geometry of an anionic ZnN2S3 chromophore. In crystalline state, the ligand moieties differ in respect of orientations and interactions while in solution they behave as identical components of a symmetric molecule. The crystal structure is stabilized by π stacking and periodic H-bonding interactions along a . The presence of a protonated azomethine N in one of the ligands is confirmed from the high conductance and acidic pH of an aqueous methanolic solution of the complex. [Copyright &y& Elsevier] |
| Copyright of Journal of Molecular Structure is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
|---|---|
| Header | DbId: egs DbLabel: Engineering Source An: 45422343 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
| IllustrationInfo | |
| Items | – Name: Title Label: Title Group: Ti Data: A structural investigation of the coordination behaviour of 4,6-dimethylpyrimidine-2-thiol with Zinc (II) at pH 6 – A zwitterionic complex exhibiting unusual ZnS<subscript>3</subscript>N<subscript>2</subscript> chromophore in solid state – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Das%2C+A%2EK%2E%22">Das, A.K.</searchLink><relatesTo>1</relatesTo><i> asishkdas2009@rediffmail.com</i><br /><searchLink fieldCode="AR" term="%22Gowda%2C+N%2ES%2E%22">Gowda, N.S.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Botoshansky%2C+M%2E%22">Botoshansky, M.</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Sridhar%2C+M%2EA%2E%22">Sridhar, M.A.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Kaftory%2C+M%2E%22">Kaftory, M.</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Prasad%2C+J%2E+Sashidhara%22">Prasad, J. Sashidhara</searchLink><relatesTo>2</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Molecular+Structure%22">Journal of Molecular Structure</searchLink>. Dec2009, Vol. 938 Issue 1-3, p259-262. 4p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Molecular+structure%22">Molecular structure</searchLink><br /><searchLink fieldCode="DE" term="%22Pyrimidines%22">Pyrimidines</searchLink><br /><searchLink fieldCode="DE" term="%22Organozinc+compounds%22">Organozinc compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen-ion+concentration%22">Hydrogen-ion concentration</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+state+chemistry%22">Solid state chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Zinc+sulfate%22">Zinc sulfate</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract: Complexation between Zn2+ and 4,6-dimethylpyrimidine-2-thiol was attempted with ZnO, ZnSO4 and Zn(OAc)2. In all cases, the same compound, tris-4,6-dimethylpyrimidine-2-thiolato zinc (II) was generated without anion incorporation. It crystallized from methanol in the space group P21/a, Z =4. The molecular structure exemplifies an uncommon coordination of 3 ligands to Zn(II) through their thiolate centres; one of the ligands is protonated to effectively form a zwitterionic complex, which exhibits capped rectangular pyramidal coordination geometry of an anionic ZnN2S3 chromophore. In crystalline state, the ligand moieties differ in respect of orientations and interactions while in solution they behave as identical components of a symmetric molecule. The crystal structure is stabilized by π stacking and periodic H-bonding interactions along a . The presence of a protonated azomethine N in one of the ligands is confirmed from the high conductance and acidic pH of an aqueous methanolic solution of the complex. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Molecular Structure is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=45422343 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.molstruc.2009.09.037 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 4 StartPage: 259 Subjects: – SubjectFull: Molecular structure Type: general – SubjectFull: Pyrimidines Type: general – SubjectFull: Organozinc compounds Type: general – SubjectFull: Metal complexes Type: general – SubjectFull: Hydrogen-ion concentration Type: general – SubjectFull: Solid state chemistry Type: general – SubjectFull: Zinc sulfate Type: general – SubjectFull: Ligands (Chemistry) Type: general Titles: – TitleFull: A structural investigation of the coordination behaviour of 4,6-dimethylpyrimidine-2-thiol with Zinc (II) at pH 6 – A zwitterionic complex exhibiting unusual ZnS3N2 chromophore in solid state Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Das, A.K. – PersonEntity: Name: NameFull: Gowda, N.S. – PersonEntity: Name: NameFull: Botoshansky, M. – PersonEntity: Name: NameFull: Sridhar, M.A. – PersonEntity: Name: NameFull: Kaftory, M. – PersonEntity: Name: NameFull: Prasad, J. Sashidhara IsPartOfRelationships: – BibEntity: Dates: – D: 16 M: 12 Text: Dec2009 Type: published Y: 2009 Identifiers: – Type: issn-print Value: 00222860 Numbering: – Type: volume Value: 938 – Type: issue Value: 1-3 Titles: – TitleFull: Journal of Molecular Structure Type: main |
| ResultId | 1 |
