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Optically Active Calixarenes Conduced by Methylene Substitution.

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Title: Optically Active Calixarenes Conduced by Methylene Substitution.
Authors: Gopalsamuthiram, Vijay1, Predeus, Alexander V.1, Huang, Rui H.1, Wulff, William D.1 wulff@chemistry.msu.edu
Source: Journal of the American Chemical Society. 12/23/2009, Vol. 131 Issue 50, p18018-18019. 2p.
Subjects: Calixarenes, Aromatic compounds, Macrocyclic compounds, Carbenes, Chemical research
Abstract: The article presents a study which examines a method for synthesizing optically active calixarenes that involves triple annulation of the biscarbene complex 5 with bisalkyne 6. The researchers utilize methylene substitution to achieve the desired results of the study. The study reveals that the method for the synthesis of optically active calixarenes using methylene substitution is also applicable for synthesizing optically active di- and tetramethoxy-substituted calixarenes.
Database: Engineering Source
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  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 47561087
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Optically Active Calixarenes Conduced by Methylene Substitution.
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  Data: <searchLink fieldCode="AR" term="%22Gopalsamuthiram%2C+Vijay%22">Gopalsamuthiram, Vijay</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Predeus%2C+Alexander+V%2E%22">Predeus, Alexander V.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Huang%2C+Rui+H%2E%22">Huang, Rui H.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Wulff%2C+William+D%2E%22">Wulff, William D.</searchLink><relatesTo>1</relatesTo><i> wulff@chemistry.msu.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 12/23/2009, Vol. 131 Issue 50, p18018-18019. 2p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Calixarenes%22">Calixarenes</searchLink><br /><searchLink fieldCode="DE" term="%22Aromatic+compounds%22">Aromatic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Macrocyclic+compounds%22">Macrocyclic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Carbenes%22">Carbenes</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+research%22">Chemical research</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The article presents a study which examines a method for synthesizing optically active calixarenes that involves triple annulation of the biscarbene complex 5 with bisalkyne 6. The researchers utilize methylene substitution to achieve the desired results of the study. The study reveals that the method for the synthesis of optically active calixarenes using methylene substitution is also applicable for synthesizing optically active di- and tetramethoxy-substituted calixarenes.
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1021/ja905990u
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 2
        StartPage: 18018
    Subjects:
      – SubjectFull: Calixarenes
        Type: general
      – SubjectFull: Aromatic compounds
        Type: general
      – SubjectFull: Macrocyclic compounds
        Type: general
      – SubjectFull: Carbenes
        Type: general
      – SubjectFull: Chemical research
        Type: general
    Titles:
      – TitleFull: Optically Active Calixarenes Conduced by Methylene Substitution.
        Type: main
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      – PersonEntity:
          Name:
            NameFull: Gopalsamuthiram, Vijay
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            NameFull: Predeus, Alexander V.
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            NameFull: Huang, Rui H.
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            NameFull: Wulff, William D.
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            – D: 23
              M: 12
              Text: 12/23/2009
              Type: published
              Y: 2009
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              Value: 131
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              Value: 50
          Titles:
            – TitleFull: Journal of the American Chemical Society
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