Application of cyclophosphazene derivatives as flame retardants for ABS

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Title: Application of cyclophosphazene derivatives as flame retardants for ABS
Authors: Shin, Young Jae1, Ham, Young Rok2, Kim, Sun Hee2, Lee, Dae Hee3, Kim, Sang Beom3, Park, Chul Soon2, Yoo, Young Mi2, Kim, Jin Gon2, Kwon, Soo Han2, Shin, Jae Sup2 jsshin@chungbuk.ac.kr
Source: Journal of Industrial & Engineering Chemistry. May2010, Vol. 16 Issue 3, p364-367. 4p.
Subjects: Cyclophosphazenes, Fireproofing agents, Halogens, Chemical reactions, Alkylbenzene sulfonates, Inorganic synthesis
Abstract: Abstract: Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene, respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LOI tests. The mechanical properties of ABS compounds containing one of these flame retardants were also examined. The derivative (HNCP) synthesized from 2,3-dihydroxynaphthalene showed the best flame retardance among these derivatives studied. Synergistic effects with novolac were observed in the cases using the derivative (PNCP) obtained from phenol, but little synergistic effects were observed in cases using HNCP. [Copyright &y& Elsevier]
Copyright of Journal of Industrial & Engineering Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 49112770
AccessLevel: 6
PubType: Periodical
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  Data: Application of cyclophosphazene derivatives as flame retardants for ABS
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  Data: <searchLink fieldCode="AR" term="%22Shin%2C+Young+Jae%22">Shin, Young Jae</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Ham%2C+Young+Rok%22">Ham, Young Rok</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Kim%2C+Sun+Hee%22">Kim, Sun Hee</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Lee%2C+Dae+Hee%22">Lee, Dae Hee</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Kim%2C+Sang+Beom%22">Kim, Sang Beom</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Park%2C+Chul+Soon%22">Park, Chul Soon</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Yoo%2C+Young+Mi%22">Yoo, Young Mi</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Kim%2C+Jin+Gon%22">Kim, Jin Gon</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Kwon%2C+Soo+Han%22">Kwon, Soo Han</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Shin%2C+Jae+Sup%22">Shin, Jae Sup</searchLink><relatesTo>2</relatesTo><i> jsshin@chungbuk.ac.kr</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Industrial+%26+Engineering+Chemistry%22">Journal of Industrial & Engineering Chemistry</searchLink>. May2010, Vol. 16 Issue 3, p364-367. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Cyclophosphazenes%22">Cyclophosphazenes</searchLink><br /><searchLink fieldCode="DE" term="%22Fireproofing+agents%22">Fireproofing agents</searchLink><br /><searchLink fieldCode="DE" term="%22Halogens%22">Halogens</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Alkylbenzene+sulfonates%22">Alkylbenzene sulfonates</searchLink><br /><searchLink fieldCode="DE" term="%22Inorganic+synthesis%22">Inorganic synthesis</searchLink>
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  Label: Abstract
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  Data: Abstract: Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene, respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LOI tests. The mechanical properties of ABS compounds containing one of these flame retardants were also examined. The derivative (HNCP) synthesized from 2,3-dihydroxynaphthalene showed the best flame retardance among these derivatives studied. Synergistic effects with novolac were observed in the cases using the derivative (PNCP) obtained from phenol, but little synergistic effects were observed in cases using HNCP. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Journal of Industrial & Engineering Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.jiec.2009.08.001
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        Text: English
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      – SubjectFull: Cyclophosphazenes
        Type: general
      – SubjectFull: Fireproofing agents
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      – SubjectFull: Halogens
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      – SubjectFull: Chemical reactions
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      – SubjectFull: Alkylbenzene sulfonates
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      – SubjectFull: Inorganic synthesis
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      – TitleFull: Application of cyclophosphazene derivatives as flame retardants for ABS
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              Text: May2010
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