Quantification of cation-exchanged zeolites by XPS and EDS: A comparative study

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Title: Quantification of cation-exchanged zeolites by XPS and EDS: A comparative study
Authors: Fibikar, Sandra1, Rinke, Matthias T.2, Schäfer, Andreas3, Cola, Luisa De1 L.decola@uni-muenster.de
Source: Microporous & Mesoporous Materials. Jul2010, Vol. 132 Issue 1/2, p296-299. 4p.
Subjects: Porous materials, Zeolites, Ion exchange (Chemistry), X-ray photoelectron spectroscopy, Comparative studies
Abstract: Abstract: Iron(II) and cesium are intercalated into zeolite L by wet impregnation. The elemental compositions of the cation-exchanged zeolite L were quantified for the first time by two different methods. X-ray Photoelectron Spectroscopy (XPS) and Energy Dispersive X-ray Spectroscopy (EDS) techniques were found to be suitable for the quantification, giving reliable results. Comparing the two different methods we found a small systematic difference in the amount of extraframework cations in zeolite L. These strategies could be applied for an easy and fast quantification of cations inside porous materials. [Copyright &y& Elsevier]
Copyright of Microporous & Mesoporous Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Quantification of cation-exchanged zeolites by XPS and EDS: A comparative study
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  Data: <searchLink fieldCode="AR" term="%22Fibikar%2C+Sandra%22">Fibikar, Sandra</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Rinke%2C+Matthias+T%2E%22">Rinke, Matthias T.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Schäfer%2C+Andreas%22">Schäfer, Andreas</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Cola%2C+Luisa+De%22">Cola, Luisa De</searchLink><relatesTo>1</relatesTo><i> L.decola@uni-muenster.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Microporous+%26+Mesoporous+Materials%22">Microporous & Mesoporous Materials</searchLink>. Jul2010, Vol. 132 Issue 1/2, p296-299. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Porous+materials%22">Porous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Zeolites%22">Zeolites</searchLink><br /><searchLink fieldCode="DE" term="%22Ion+exchange+%28Chemistry%29%22">Ion exchange (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+photoelectron+spectroscopy%22">X-ray photoelectron spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Comparative+studies%22">Comparative studies</searchLink>
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  Label: Abstract
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  Data: Abstract: Iron(II) and cesium are intercalated into zeolite L by wet impregnation. The elemental compositions of the cation-exchanged zeolite L were quantified for the first time by two different methods. X-ray Photoelectron Spectroscopy (XPS) and Energy Dispersive X-ray Spectroscopy (EDS) techniques were found to be suitable for the quantification, giving reliable results. Comparing the two different methods we found a small systematic difference in the amount of extraframework cations in zeolite L. These strategies could be applied for an easy and fast quantification of cations inside porous materials. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Microporous & Mesoporous Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.micromeso.2010.02.016
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Zeolites
        Type: general
      – SubjectFull: Ion exchange (Chemistry)
        Type: general
      – SubjectFull: X-ray photoelectron spectroscopy
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      – SubjectFull: Comparative studies
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      – TitleFull: Quantification of cation-exchanged zeolites by XPS and EDS: A comparative study
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              Text: Jul2010
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              Y: 2010
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