Ion–ion coincidence experiments with low extraction fields

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Title: Ion–ion coincidence experiments with low extraction fields
Authors: Flammini, R. roberto.flammini@imip.cnr.it, Fainelli, E.1, Avaldi, L.1
Source: Journal of Electron Spectroscopy & Related Phenomena. Jun2010, Vol. 180 Issue 1-3, p39-45. 7p.
Subjects: Fragmentation reactions, Monte Carlo method, Simulation methods & models, Ions, Methane, Separation (Technology), Hydrogen
Abstract: Abstract: The fragmentation of a polyatomic molecular dication has been investigated by means of a Monte Carlo simulation which can take into account realistic experimental conditions. The simulation applied to the three body process CH4 2+ →CH2 + +H+ +H shows that the low angular acceptance, consequence of the low extraction field, does not prevent the distinction between the initial charge separation and the synchronous concerted decay mechanisms, which lead to the same final state. The comparison of the results with recent experiments confirms that an initial charge separation with a following loss of a hydrogen atom describes better the experimental observations. [Copyright &y& Elsevier]
Copyright of Journal of Electron Spectroscopy & Related Phenomena is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 51292692
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  Data: Ion–ion coincidence experiments with low extraction fields
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  Data: <searchLink fieldCode="AR" term="%22Flammini%2C+R%2E%22">Flammini, R.</searchLink><i> roberto.flammini@imip.cnr.it</i><br /><searchLink fieldCode="AR" term="%22Fainelli%2C+E%2E%22">Fainelli, E.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Avaldi%2C+L%2E%22">Avaldi, L.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Electron+Spectroscopy+%26+Related+Phenomena%22">Journal of Electron Spectroscopy & Related Phenomena</searchLink>. Jun2010, Vol. 180 Issue 1-3, p39-45. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Fragmentation+reactions%22">Fragmentation reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Monte+Carlo+method%22">Monte Carlo method</searchLink><br /><searchLink fieldCode="DE" term="%22Simulation+methods+%26+models%22">Simulation methods & models</searchLink><br /><searchLink fieldCode="DE" term="%22Ions%22">Ions</searchLink><br /><searchLink fieldCode="DE" term="%22Methane%22">Methane</searchLink><br /><searchLink fieldCode="DE" term="%22Separation+%28Technology%29%22">Separation (Technology)</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen%22">Hydrogen</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Abstract: The fragmentation of a polyatomic molecular dication has been investigated by means of a Monte Carlo simulation which can take into account realistic experimental conditions. The simulation applied to the three body process CH4 2+ →CH2 + +H+ +H shows that the low angular acceptance, consequence of the low extraction field, does not prevent the distinction between the initial charge separation and the synchronous concerted decay mechanisms, which lead to the same final state. The comparison of the results with recent experiments confirms that an initial charge separation with a following loss of a hydrogen atom describes better the experimental observations. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Electron Spectroscopy & Related Phenomena is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.elspec.2010.03.015
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      – Code: eng
        Text: English
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        PageCount: 7
        StartPage: 39
    Subjects:
      – SubjectFull: Fragmentation reactions
        Type: general
      – SubjectFull: Monte Carlo method
        Type: general
      – SubjectFull: Simulation methods & models
        Type: general
      – SubjectFull: Ions
        Type: general
      – SubjectFull: Methane
        Type: general
      – SubjectFull: Separation (Technology)
        Type: general
      – SubjectFull: Hydrogen
        Type: general
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      – TitleFull: Ion–ion coincidence experiments with low extraction fields
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            NameFull: Flammini, R.
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            NameFull: Fainelli, E.
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            – D: 01
              M: 06
              Text: Jun2010
              Type: published
              Y: 2010
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            – TitleFull: Journal of Electron Spectroscopy & Related Phenomena
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