View in EDS

Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex.

Saved in:
Bibliographic Details
Title: Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex.
Authors: Valerie J. Scott1, Jay A. Labinger1, John E. Bercaw1
Source: Organometallics. Sep2010, Vol. 29 Issue 18, p4090-4096. 7p.
Subjects: Iodides, Methyl groups, Metal complexes, Gold, Oxidation, Nucleophilic reactions, Chemical reduction
Abstract: Oxidation of (Idipp)AuMe (Idipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with I2gives a monomethyl Au(III) complex, (Idipp)AuI2Me, which decomposes cleanly to MeI and (Idipp)AuI. Kinetics experiments show that this transformation occurs primarily via three-coordinate, cationic [(Idipp)AuIMe]+, which undergoes intramolecular reductive elimination rather than nucleophilic attack by external I−. [ABSTRACT FROM AUTHOR]
Copyright of Organometallics is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 54100306
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Valerie+J%2E+Scott%22">Valerie J. Scott</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Jay+A%2E+Labinger%22">Jay A. Labinger</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22John+E%2E+Bercaw%22">John E. Bercaw</searchLink><relatesTo>1</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Organometallics%22">Organometallics</searchLink>. Sep2010, Vol. 29 Issue 18, p4090-4096. 7p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Iodides%22">Iodides</searchLink><br /><searchLink fieldCode="DE" term="%22Methyl+groups%22">Methyl groups</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Gold%22">Gold</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation%22">Oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Nucleophilic+reactions%22">Nucleophilic reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reduction%22">Chemical reduction</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Oxidation of (Idipp)AuMe (Idipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with I2gives a monomethyl Au(III) complex, (Idipp)AuI2Me, which decomposes cleanly to MeI and (Idipp)AuI. Kinetics experiments show that this transformation occurs primarily via three-coordinate, cationic [(Idipp)AuIMe]+, which undergoes intramolecular reductive elimination rather than nucleophilic attack by external I−. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Organometallics is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=54100306
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1021/om1006566
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 7
        StartPage: 4090
    Subjects:
      – SubjectFull: Iodides
        Type: general
      – SubjectFull: Methyl groups
        Type: general
      – SubjectFull: Metal complexes
        Type: general
      – SubjectFull: Gold
        Type: general
      – SubjectFull: Oxidation
        Type: general
      – SubjectFull: Nucleophilic reactions
        Type: general
      – SubjectFull: Chemical reduction
        Type: general
    Titles:
      – TitleFull: Mechanism of Reductive Elimination of Methyl Iodide from a Novel Gold(III)−Monomethyl Complex.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Valerie J. Scott
      – PersonEntity:
          Name:
            NameFull: Jay A. Labinger
      – PersonEntity:
          Name:
            NameFull: John E. Bercaw
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 27
              M: 09
              Text: Sep2010
              Type: published
              Y: 2010
          Identifiers:
            – Type: issn-print
              Value: 02767333
          Numbering:
            – Type: volume
              Value: 29
            – Type: issue
              Value: 18
          Titles:
            – TitleFull: Organometallics
              Type: main
ResultId 1