The effect of reaction conditions on the nature of cadmium 1,3,5-benzenetricarboxylate metal–organic frameworks
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| Title: | The effect of reaction conditions on the nature of cadmium 1,3,5-benzenetricarboxylate metal–organic frameworks |
|---|---|
| Authors: | Burrows, Andrew D.1 a.d.burrows@bath.ac.uk, Frost, Christopher G.1, Kandiah, Mathivathani1, Keenan, Luke L.1, Mahon, Mary F.1, Savarese, Teresa L.1, Warren, John E.2 |
| Source: | Inorganica Chimica Acta. Jan2011, Vol. 366 Issue 1, p303-309. 7p. |
| Subjects: | Cadmium, Carboxylic acids, Benzene, Temperature effect, Ligands (Chemistry), Pyrazines, Coordination polymers |
| Abstract: | Abstract: The product from the reaction between Cd(NO3)2·4H2O and 1,3,5-benzenetricarboxylic acid (H3btc) in DMF at 95°C depends on the reaction time, with [Cd(Hbtc)(H2O)2] 1 and [Cd(Hbtc)(DMF)2] 2 isolated after heating for 10min, the latter after standing the solution for 1–2weeks at room temperature. [Cd3(btc)2(H2O)9]·4H2O 3 was isolated after heating for 1h, whereas [Cd12(btc)8(DMF)14(OH2)2]·1.5DMF 4 was isolated after heating for 2days. Compounds 1 and 3 have been previously reported, whereas 2 and 4 are both new. Compound 2 adopts a two-dimensional sheet structure, with the coordinated DMF ligands projecting from both sides of the sheets, whereas 4 has a complex three-dimensional structure related to the fsc net. When the reaction was repeated in the presence of pyrazine (pyz), the product [Cd(Hbtc)(pyz)(DMF)]·DMF 5 was isolated as a minor compound. Compound 5 has a two-dimensional structure, with Cd-Hbtc zig-zag chains linked into sheets through the pyrazine ligands. [ABSTRACT FROM AUTHOR] |
| Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 57300770 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: The effect of reaction conditions on the nature of cadmium 1,3,5-benzenetricarboxylate metal–organic frameworks – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Burrows%2C+Andrew+D%2E%22">Burrows, Andrew D.</searchLink><relatesTo>1</relatesTo><i> a.d.burrows@bath.ac.uk</i><br /><searchLink fieldCode="AR" term="%22Frost%2C+Christopher+G%2E%22">Frost, Christopher G.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kandiah%2C+Mathivathani%22">Kandiah, Mathivathani</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Keenan%2C+Luke+L%2E%22">Keenan, Luke L.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Mahon%2C+Mary+F%2E%22">Mahon, Mary F.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Savarese%2C+Teresa+L%2E%22">Savarese, Teresa L.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Warren%2C+John+E%2E%22">Warren, John E.</searchLink><relatesTo>2</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Inorganica+Chimica+Acta%22">Inorganica Chimica Acta</searchLink>. Jan2011, Vol. 366 Issue 1, p303-309. 7p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Cadmium%22">Cadmium</searchLink><br /><searchLink fieldCode="DE" term="%22Carboxylic+acids%22">Carboxylic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Benzene%22">Benzene</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature+effect%22">Temperature effect</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Pyrazines%22">Pyrazines</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+polymers%22">Coordination polymers</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Abstract: The product from the reaction between Cd(NO3)2·4H2O and 1,3,5-benzenetricarboxylic acid (H3btc) in DMF at 95°C depends on the reaction time, with [Cd(Hbtc)(H2O)2] 1 and [Cd(Hbtc)(DMF)2] 2 isolated after heating for 10min, the latter after standing the solution for 1–2weeks at room temperature. [Cd3(btc)2(H2O)9]·4H2O 3 was isolated after heating for 1h, whereas [Cd12(btc)8(DMF)14(OH2)2]·1.5DMF 4 was isolated after heating for 2days. Compounds 1 and 3 have been previously reported, whereas 2 and 4 are both new. Compound 2 adopts a two-dimensional sheet structure, with the coordinated DMF ligands projecting from both sides of the sheets, whereas 4 has a complex three-dimensional structure related to the fsc net. When the reaction was repeated in the presence of pyrazine (pyz), the product [Cd(Hbtc)(pyz)(DMF)]·DMF 5 was isolated as a minor compound. Compound 5 has a two-dimensional structure, with Cd-Hbtc zig-zag chains linked into sheets through the pyrazine ligands. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Inorganica Chimica Acta is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.ica.2010.11.025 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 7 StartPage: 303 Subjects: – SubjectFull: Cadmium Type: general – SubjectFull: Carboxylic acids Type: general – SubjectFull: Benzene Type: general – SubjectFull: Temperature effect Type: general – SubjectFull: Ligands (Chemistry) Type: general – SubjectFull: Pyrazines Type: general – SubjectFull: Coordination polymers Type: general Titles: – TitleFull: The effect of reaction conditions on the nature of cadmium 1,3,5-benzenetricarboxylate metal–organic frameworks Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Burrows, Andrew D. – PersonEntity: Name: NameFull: Frost, Christopher G. – PersonEntity: Name: NameFull: Kandiah, Mathivathani – PersonEntity: Name: NameFull: Keenan, Luke L. – PersonEntity: Name: NameFull: Mahon, Mary F. – PersonEntity: Name: NameFull: Savarese, Teresa L. – PersonEntity: Name: NameFull: Warren, John E. IsPartOfRelationships: – BibEntity: Dates: – D: 30 M: 01 Text: Jan2011 Type: published Y: 2011 Identifiers: – Type: issn-print Value: 00201693 Numbering: – Type: volume Value: 366 – Type: issue Value: 1 Titles: – TitleFull: Inorganica Chimica Acta Type: main |
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