Detailed analytical study of radiolysis products of simple organic compounds as a methodological approach to investigate prebiotic chemistry—Part 2

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Title: Detailed analytical study of radiolysis products of simple organic compounds as a methodological approach to investigate prebiotic chemistry—Part 2
Authors: Dondi, D.1 dondi@unipv.it, Merli, D.1, Pretali, L.2, Buttafava, A.1, Faucitano, A.1
Source: Radiation Physics & Chemistry. Mar2011, Vol. 80 Issue 3, p408-413. 6p.
Subjects: Radiation chemistry, Organic compounds, Solution (Chemistry), Ammonia, Acetone, Gamma rays, Irradiation, Analytical chemistry, Amino acids, Reaction mechanisms (Chemistry)
Abstract: Abstract: Aqueous solutions of acetone and ammonia, presumably present on the primordial Earth, were submitted to 60Co gamma irradiation (total dose 800kGy). Among other products, hexamethylenetetramine (HMT) was detected in appreciable quantity. Since the latter is considered an amino acid precursor and HMT was identified on simulation of cometary ices, a study of its radiation stability was undertaken. Plausible reaction pathways leading to major compounds were proposed, supported by literature data. [ABSTRACT FROM AUTHOR]
Copyright of Radiation Physics & Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Detailed analytical study of radiolysis products of simple organic compounds as a methodological approach to investigate prebiotic chemistry—Part 2
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  Data: <searchLink fieldCode="JN" term="%22Radiation+Physics+%26+Chemistry%22">Radiation Physics & Chemistry</searchLink>. Mar2011, Vol. 80 Issue 3, p408-413. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Radiation+chemistry%22">Radiation chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+compounds%22">Organic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Solution+%28Chemistry%29%22">Solution (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Ammonia%22">Ammonia</searchLink><br /><searchLink fieldCode="DE" term="%22Acetone%22">Acetone</searchLink><br /><searchLink fieldCode="DE" term="%22Gamma+rays%22">Gamma rays</searchLink><br /><searchLink fieldCode="DE" term="%22Irradiation%22">Irradiation</searchLink><br /><searchLink fieldCode="DE" term="%22Analytical+chemistry%22">Analytical chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Amino+acids%22">Amino acids</searchLink><br /><searchLink fieldCode="DE" term="%22Reaction+mechanisms+%28Chemistry%29%22">Reaction mechanisms (Chemistry)</searchLink>
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  Data: Abstract: Aqueous solutions of acetone and ammonia, presumably present on the primordial Earth, were submitted to 60Co gamma irradiation (total dose 800kGy). Among other products, hexamethylenetetramine (HMT) was detected in appreciable quantity. Since the latter is considered an amino acid precursor and HMT was identified on simulation of cometary ices, a study of its radiation stability was undertaken. Plausible reaction pathways leading to major compounds were proposed, supported by literature data. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Radiation Physics & Chemistry is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.radphyschem.2010.09.011
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Organic compounds
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      – SubjectFull: Solution (Chemistry)
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      – SubjectFull: Amino acids
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      – SubjectFull: Reaction mechanisms (Chemistry)
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      – TitleFull: Detailed analytical study of radiolysis products of simple organic compounds as a methodological approach to investigate prebiotic chemistry—Part 2
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              Text: Mar2011
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