Evaluation of the application conditions of artificial protection treatments on salt-laden limestones and marble

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Title: Evaluation of the application conditions of artificial protection treatments on salt-laden limestones and marble
Authors: Pinna, Daniela1 daniela.pinna@beniculturali.it, Salvadori, Barbara1,2, Porcinai, Simone1
Source: Construction & Building Materials. May2011, Vol. 25 Issue 5, p2723-2732. 10p.
Subjects: Limestone, Marble, Soluble salts, Ammonium compounds, Polydimethylsiloxane, Construction materials, Surface analysis
Abstract: Abstract: Soluble salts contaminating limestones and marbles used as building and artistic materials play a relevant role in the deterioration processes of the substrates. Although desalination operations are carried out prior to protection and/or consolidation, a certain amount of salt remains inside the stones. When a surface treatment is chosen, the evaluation of its compatibility with the residual saline content is therefore needed. In the present work, specimens of three lithotypes characterized by a very different porosity –Lecce stone and Ançã stone, both highly porous, and the less porous Gioia marble – were contaminated with salt and then treated with two protective products, the organic polydimethylsiloxane and the inorganic ammonium oxalate (NH4)2(COO)2·H2O. Aim of the research was to select the best application conditions of the two products on salt-laden stone specimens, investigating as well the dependence of the protective action on the procedures adopted to apply the products. The performance of different concentrations and contact times of the products was tested in the laboratory, paying special attention to the possible drawbacks due to the salt. The study was carried out applying different methods: colorimetric measurements before and after the application of the products; water absorption by capillarity to investigate variations in water-interaction features; SEM–EDS analyses to evaluate the distribution of products and salt on the substrates. [Copyright &y& Elsevier]
Copyright of Construction & Building Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 57681878
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PubType: Academic Journal
PubTypeId: academicJournal
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  Label: Title
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  Data: Evaluation of the application conditions of artificial protection treatments on salt-laden limestones and marble
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  Data: <searchLink fieldCode="AR" term="%22Pinna%2C+Daniela%22">Pinna, Daniela</searchLink><relatesTo>1</relatesTo><i> daniela.pinna@beniculturali.it</i><br /><searchLink fieldCode="AR" term="%22Salvadori%2C+Barbara%22">Salvadori, Barbara</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Porcinai%2C+Simone%22">Porcinai, Simone</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Construction+%26+Building+Materials%22">Construction & Building Materials</searchLink>. May2011, Vol. 25 Issue 5, p2723-2732. 10p.
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  Data: <searchLink fieldCode="DE" term="%22Limestone%22">Limestone</searchLink><br /><searchLink fieldCode="DE" term="%22Marble%22">Marble</searchLink><br /><searchLink fieldCode="DE" term="%22Soluble+salts%22">Soluble salts</searchLink><br /><searchLink fieldCode="DE" term="%22Ammonium+compounds%22">Ammonium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Polydimethylsiloxane%22">Polydimethylsiloxane</searchLink><br /><searchLink fieldCode="DE" term="%22Construction+materials%22">Construction materials</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+analysis%22">Surface analysis</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Abstract: Soluble salts contaminating limestones and marbles used as building and artistic materials play a relevant role in the deterioration processes of the substrates. Although desalination operations are carried out prior to protection and/or consolidation, a certain amount of salt remains inside the stones. When a surface treatment is chosen, the evaluation of its compatibility with the residual saline content is therefore needed. In the present work, specimens of three lithotypes characterized by a very different porosity –Lecce stone and Ançã stone, both highly porous, and the less porous Gioia marble – were contaminated with salt and then treated with two protective products, the organic polydimethylsiloxane and the inorganic ammonium oxalate (NH4)2(COO)2·H2O. Aim of the research was to select the best application conditions of the two products on salt-laden stone specimens, investigating as well the dependence of the protective action on the procedures adopted to apply the products. The performance of different concentrations and contact times of the products was tested in the laboratory, paying special attention to the possible drawbacks due to the salt. The study was carried out applying different methods: colorimetric measurements before and after the application of the products; water absorption by capillarity to investigate variations in water-interaction features; SEM–EDS analyses to evaluate the distribution of products and salt on the substrates. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Construction & Building Materials is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.conbuildmat.2010.12.023
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      – Code: eng
        Text: English
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        PageCount: 10
        StartPage: 2723
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      – SubjectFull: Limestone
        Type: general
      – SubjectFull: Marble
        Type: general
      – SubjectFull: Soluble salts
        Type: general
      – SubjectFull: Ammonium compounds
        Type: general
      – SubjectFull: Polydimethylsiloxane
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      – SubjectFull: Construction materials
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      – SubjectFull: Surface analysis
        Type: general
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      – TitleFull: Evaluation of the application conditions of artificial protection treatments on salt-laden limestones and marble
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            NameFull: Pinna, Daniela
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            NameFull: Salvadori, Barbara
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            NameFull: Porcinai, Simone
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            – D: 01
              M: 05
              Text: May2011
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              Y: 2011
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