Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications.
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| Title: | Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications. |
|---|---|
| Authors: | Burrows, Andrew D.1 |
| Source: | CrystEngComm. May2011, Vol. 13 Issue 10, p3623-3642. 20p. |
| Subjects: | Structural frames, Surfaces (Technology), Metals, Mixtures, Solid solutions, Crystallography |
| Abstract: | Mixed-component metal–organic frameworks (MC-MOFs) are metal–organic frameworks that have different linkers or metals with the same structural role. Many of these mixed-ligand or mixed-metal MOFs are solid solutions, in which the proportions of the ligands or metals can be adjusted or even controlled. These MC-MOFs can be prepared directly, using more than one metal or ligand in the synthesis, or formed by post-synthetic modification. A second class of MC-MOFs have core–shell structures, and these can be prepared through epitaxial growth of one MOF on the surface of another or post-synthetic modification of the crystal surfaces. This review describes the syntheses, structures and properties of mixed-ligand, mixed-metal and core–shell MOFs, and highlights some of the potential benefits in functionality that these materials have. [ABSTRACT FROM AUTHOR] |
| Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 60690321 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Burrows%2C+Andrew+D%2E%22">Burrows, Andrew D.</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22CrystEngComm%22">CrystEngComm</searchLink>. May2011, Vol. 13 Issue 10, p3623-3642. 20p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Structural+frames%22">Structural frames</searchLink><br /><searchLink fieldCode="DE" term="%22Surfaces+%28Technology%29%22">Surfaces (Technology)</searchLink><br /><searchLink fieldCode="DE" term="%22Metals%22">Metals</searchLink><br /><searchLink fieldCode="DE" term="%22Mixtures%22">Mixtures</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+solutions%22">Solid solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallography%22">Crystallography</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Mixed-component metal–organic frameworks (MC-MOFs) are metal–organic frameworks that have different linkers or metals with the same structural role. Many of these mixed-ligand or mixed-metal MOFs are solid solutions, in which the proportions of the ligands or metals can be adjusted or even controlled. These MC-MOFs can be prepared directly, using more than one metal or ligand in the synthesis, or formed by post-synthetic modification. A second class of MC-MOFs have core–shell structures, and these can be prepared through epitaxial growth of one MOF on the surface of another or post-synthetic modification of the crystal surfaces. This review describes the syntheses, structures and properties of mixed-ligand, mixed-metal and core–shell MOFs, and highlights some of the potential benefits in functionality that these materials have. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1039/c0ce00568a Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 20 StartPage: 3623 Subjects: – SubjectFull: Structural frames Type: general – SubjectFull: Surfaces (Technology) Type: general – SubjectFull: Metals Type: general – SubjectFull: Mixtures Type: general – SubjectFull: Solid solutions Type: general – SubjectFull: Crystallography Type: general Titles: – TitleFull: Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Burrows, Andrew D. IsPartOfRelationships: – BibEntity: Dates: – D: 17 M: 05 Text: May2011 Type: published Y: 2011 Identifiers: – Type: issn-print Value: 14668033 Numbering: – Type: volume Value: 13 – Type: issue Value: 10 Titles: – TitleFull: CrystEngComm Type: main |
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