Effect of Soybean Oil Fatty Acid Composition and Selenium Application on Biodiesel Properties.

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Title: Effect of Soybean Oil Fatty Acid Composition and Selenium Application on Biodiesel Properties.
Authors: Fallen, Benjamin1, Pantalone, Vincent1 vpantalo@utk.edu, Sams, Carl1, Kopsell, Dean1, Vaughn, Steven2, Moser, Bryan2
Source: Journal of the American Oil Chemists' Society (JAOCS). Jul2011, Vol. 88 Issue 7, p1019-1028. 10p.
Subjects: Soy oil, Selenium, Biodiesel fuels, Unsaturated fatty acids, Antioxidants, Peroxides, Viscosity, Oxidation
Abstract: Biodiesel consisting principally of monounsaturated fatty acid methyl esters (FAME) has been reported to have the optimal balance between cold flow properties and oxidative stability, therefore producing a superior fuel. In addition, treating biodiesel with antioxidants such as selenium (Se) also increases oxidative stability. Fuel properties including acid value (AV), cloud point (CP), iodine value (IV), pour point (PP), peroxide value (PV), induction period (IP), onset temperature (OT), and kinematic viscosity (KV) were used to evaluate a newly developed Roundup Ready soybean recombinant inbred line (RIL) and a commercial cultivar. The RIL had a fatty acid profile with elevated levels of monounsaturated FAME. TN07-93RR was determined as the more desirable line for production of biodiesel, based on its fatty acid composition and subsequent fuel properties. The commercial cultivar AG3906 contained the highest abundance of polyunsaturated FAME and exhibited comparatively high IV and low oxidative stability. AG3906 was therefore not acceptable under the European biodiesel standard, EN 14214. However, TN07-93RR and AG3906 both were considered satisfactory according to the American biodiesel standard, ASTM D6751. Foliar treatment of soybean plants with varying amounts of Se had no effect on subsequent biodiesel oxidative stabilities. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Oil Chemists' Society (JAOCS) is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Effect of Soybean Oil Fatty Acid Composition and Selenium Application on Biodiesel Properties.
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  Data: <searchLink fieldCode="AR" term="%22Fallen%2C+Benjamin%22">Fallen, Benjamin</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Pantalone%2C+Vincent%22">Pantalone, Vincent</searchLink><relatesTo>1</relatesTo><i> vpantalo@utk.edu</i><br /><searchLink fieldCode="AR" term="%22Sams%2C+Carl%22">Sams, Carl</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kopsell%2C+Dean%22">Kopsell, Dean</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Vaughn%2C+Steven%22">Vaughn, Steven</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Moser%2C+Bryan%22">Moser, Bryan</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Oil+Chemists'+Society+%28JAOCS%29%22">Journal of the American Oil Chemists' Society (JAOCS)</searchLink>. Jul2011, Vol. 88 Issue 7, p1019-1028. 10p.
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  Data: <searchLink fieldCode="DE" term="%22Soy+oil%22">Soy oil</searchLink><br /><searchLink fieldCode="DE" term="%22Selenium%22">Selenium</searchLink><br /><searchLink fieldCode="DE" term="%22Biodiesel+fuels%22">Biodiesel fuels</searchLink><br /><searchLink fieldCode="DE" term="%22Unsaturated+fatty+acids%22">Unsaturated fatty acids</searchLink><br /><searchLink fieldCode="DE" term="%22Antioxidants%22">Antioxidants</searchLink><br /><searchLink fieldCode="DE" term="%22Peroxides%22">Peroxides</searchLink><br /><searchLink fieldCode="DE" term="%22Viscosity%22">Viscosity</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation%22">Oxidation</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Biodiesel consisting principally of monounsaturated fatty acid methyl esters (FAME) has been reported to have the optimal balance between cold flow properties and oxidative stability, therefore producing a superior fuel. In addition, treating biodiesel with antioxidants such as selenium (Se) also increases oxidative stability. Fuel properties including acid value (AV), cloud point (CP), iodine value (IV), pour point (PP), peroxide value (PV), induction period (IP), onset temperature (OT), and kinematic viscosity (KV) were used to evaluate a newly developed Roundup Ready soybean recombinant inbred line (RIL) and a commercial cultivar. The RIL had a fatty acid profile with elevated levels of monounsaturated FAME. TN07-93RR was determined as the more desirable line for production of biodiesel, based on its fatty acid composition and subsequent fuel properties. The commercial cultivar AG3906 contained the highest abundance of polyunsaturated FAME and exhibited comparatively high IV and low oxidative stability. AG3906 was therefore not acceptable under the European biodiesel standard, EN 14214. However, TN07-93RR and AG3906 both were considered satisfactory according to the American biodiesel standard, ASTM D6751. Foliar treatment of soybean plants with varying amounts of Se had no effect on subsequent biodiesel oxidative stabilities. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of the American Oil Chemists' Society (JAOCS) is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s11746-010-1746-z
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 10
        StartPage: 1019
    Subjects:
      – SubjectFull: Soy oil
        Type: general
      – SubjectFull: Selenium
        Type: general
      – SubjectFull: Biodiesel fuels
        Type: general
      – SubjectFull: Unsaturated fatty acids
        Type: general
      – SubjectFull: Antioxidants
        Type: general
      – SubjectFull: Peroxides
        Type: general
      – SubjectFull: Viscosity
        Type: general
      – SubjectFull: Oxidation
        Type: general
    Titles:
      – TitleFull: Effect of Soybean Oil Fatty Acid Composition and Selenium Application on Biodiesel Properties.
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            NameFull: Fallen, Benjamin
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            NameFull: Pantalone, Vincent
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            NameFull: Sams, Carl
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            NameFull: Kopsell, Dean
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              M: 07
              Text: Jul2011
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              Y: 2011
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