View in EDS

Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridineElectronic supplementary information (ESI) available. CCDC reference numbers 818774–818781. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05352c

Saved in:
Bibliographic Details
Title: Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridineElectronic supplementary information (ESI) available. CCDC reference numbers 818774–818781. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05352c
Authors: Christopher J. Adams1, Mairi F. Haddow1, David J. Harding2, Thomas J. Podesta1, Rachel E. Waddington1
Source: CrystEngComm. Jul2011, Vol. 13 Issue 15, p4909-4914. 6p.
Subjects: Iron compounds, Crystallography, Chemical reactions, Bipyridine, Solvents, Methanol, Monomers, Stoichiometry, Acetonitrile
Abstract: A number of different compounds have been synthesised by reaction of solutions containing Fe(NCE)2(E = S, Se) with solutions containing 3,3′-bipyridine. When the solvent used is methanol, the products are the monomeric compounds trans-{Fe(NCS)2(3,3′-bipy)2(MeOH)2} 1or trans-{Fe(NCSe)2(3,3′-bipy)2(MeOH)2} 2, but when acetonitrile is used the layered coordination network {Fe(NCS)2(3,3′-bipy)2} 3or doubly interpenetrated coordination network {Fe(NCSe)2(3,3′-bipy)2} 4is formed instead. Using methanol to dissolve the Fe(NCE)2and CHX3(X = Cl, Br) to dissolve the 3,3′-bipyridine yields solvated coordination networks of stoichiometry {Fe(NCE)2(3,3′-bipy)2}·2CHX3. The crystal structures of all of these compounds except 4are presented. [ABSTRACT FROM AUTHOR]
Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 62653031
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridineElectronic supplementary information (ESI) available. CCDC reference numbers 818774–818781. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05352c
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Christopher+J%2E+Adams%22">Christopher J. Adams</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Mairi+F%2E+Haddow%22">Mairi F. Haddow</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22David+J%2E+Harding%22">David J. Harding</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Thomas+J%2E+Podesta%22">Thomas J. Podesta</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Rachel+E%2E+Waddington%22">Rachel E. Waddington</searchLink><relatesTo>1</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22CrystEngComm%22">CrystEngComm</searchLink>. Jul2011, Vol. 13 Issue 15, p4909-4914. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Iron+compounds%22">Iron compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallography%22">Crystallography</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Bipyridine%22">Bipyridine</searchLink><br /><searchLink fieldCode="DE" term="%22Solvents%22">Solvents</searchLink><br /><searchLink fieldCode="DE" term="%22Methanol%22">Methanol</searchLink><br /><searchLink fieldCode="DE" term="%22Monomers%22">Monomers</searchLink><br /><searchLink fieldCode="DE" term="%22Stoichiometry%22">Stoichiometry</searchLink><br /><searchLink fieldCode="DE" term="%22Acetonitrile%22">Acetonitrile</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A number of different compounds have been synthesised by reaction of solutions containing Fe(NCE)2(E = S, Se) with solutions containing 3,3′-bipyridine. When the solvent used is methanol, the products are the monomeric compounds trans-{Fe(NCS)2(3,3′-bipy)2(MeOH)2} 1or trans-{Fe(NCSe)2(3,3′-bipy)2(MeOH)2} 2, but when acetonitrile is used the layered coordination network {Fe(NCS)2(3,3′-bipy)2} 3or doubly interpenetrated coordination network {Fe(NCSe)2(3,3′-bipy)2} 4is formed instead. Using methanol to dissolve the Fe(NCE)2and CHX3(X = Cl, Br) to dissolve the 3,3′-bipyridine yields solvated coordination networks of stoichiometry {Fe(NCE)2(3,3′-bipy)2}·2CHX3. The crystal structures of all of these compounds except 4are presented. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of CrystEngComm is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=62653031
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1039/c1ce05352c
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 4909
    Subjects:
      – SubjectFull: Iron compounds
        Type: general
      – SubjectFull: Crystallography
        Type: general
      – SubjectFull: Chemical reactions
        Type: general
      – SubjectFull: Bipyridine
        Type: general
      – SubjectFull: Solvents
        Type: general
      – SubjectFull: Methanol
        Type: general
      – SubjectFull: Monomers
        Type: general
      – SubjectFull: Stoichiometry
        Type: general
      – SubjectFull: Acetonitrile
        Type: general
    Titles:
      – TitleFull: Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridineElectronic supplementary information (ESI) available. CCDC reference numbers 818774–818781. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05352c
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Christopher J. Adams
      – PersonEntity:
          Name:
            NameFull: Mairi F. Haddow
      – PersonEntity:
          Name:
            NameFull: David J. Harding
      – PersonEntity:
          Name:
            NameFull: Thomas J. Podesta
      – PersonEntity:
          Name:
            NameFull: Rachel E. Waddington
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 11
              M: 07
              Text: Jul2011
              Type: published
              Y: 2011
          Identifiers:
            – Type: issn-print
              Value: 14668033
          Numbering:
            – Type: volume
              Value: 13
            – Type: issue
              Value: 15
          Titles:
            – TitleFull: CrystEngComm
              Type: main
ResultId 1