Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridineElectronic supplementary information (ESI) available. CCDC reference numbers 818774–818781. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05352c
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| Title: | Iron(ii) thio- and selenocyanate coordination networks containing 3,3′-bipyridineElectronic supplementary information (ESI) available. CCDC reference numbers 818774–818781. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05352c |
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| Authors: | Christopher J. Adams1, Mairi F. Haddow1, David J. Harding2, Thomas J. Podesta1, Rachel E. Waddington1 |
| Source: | CrystEngComm. Jul2011, Vol. 13 Issue 15, p4909-4914. 6p. |
| Subjects: | Iron compounds, Crystallography, Chemical reactions, Bipyridine, Solvents, Methanol, Monomers, Stoichiometry, Acetonitrile |
| Abstract: | A number of different compounds have been synthesised by reaction of solutions containing Fe(NCE)2(E = S, Se) with solutions containing 3,3′-bipyridine. When the solvent used is methanol, the products are the monomeric compounds trans-{Fe(NCS)2(3,3′-bipy)2(MeOH)2} 1or trans-{Fe(NCSe)2(3,3′-bipy)2(MeOH)2} 2, but when acetonitrile is used the layered coordination network {Fe(NCS)2(3,3′-bipy)2} 3or doubly interpenetrated coordination network {Fe(NCSe)2(3,3′-bipy)2} 4is formed instead. Using methanol to dissolve the Fe(NCE)2and CHX3(X = Cl, Br) to dissolve the 3,3′-bipyridine yields solvated coordination networks of stoichiometry {Fe(NCE)2(3,3′-bipy)2}·2CHX3. The crystal structures of all of these compounds except 4are presented. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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