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Development of cadmium/silver/palladium separation by ion chromatography with quadrupole inductively coupled plasma mass spectrometry detection for off-line cadmium isotopic measurements

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Title: Development of cadmium/silver/palladium separation by ion chromatography with quadrupole inductively coupled plasma mass spectrometry detection for off-line cadmium isotopic measurements
Authors: Gautier, C. celine.gautier@cea.fr, Bourgeois, M.1, Isnard, H.1, Nonell, A.1, Stadelmann, G.1, Goutelard, F.1
Source: Journal of Chromatography A. Aug2011, Vol. 1218 Issue 31, p5241-5247. 7p.
Subjects: Ion exchange chromatography, Phase partition, Transition metals, Inductively coupled plasma mass spectrometry, Cadmium isotopes, Carboxylic acids, Functional groups, Transmutation (Chemistry)
Abstract: Abstract: A separation method was investigated to perform off-line cadmium isotopic measurements on a 109Ag transmutation target. Ion chromatography (IC) with Q ICPMS detection (quadrupole inductively coupled plasma mass spectrometry detection) was chosen to separate cadmium from the isobarically interfering elements, silver and palladium, present in the sample. The optimization of chromatographic conditions was particularly studied. Several anion and cation columns (Dionex AG11®, CS10® and CS12®) were compared with different mobile phases (HNO3, HCl). The separation procedure was achieved with a carboxylate-functionalized cation exchange CS12 column using 0.5M HNO3 as eluent. The developed technique yielded satisfactory results in terms of separation factors (greater than 5) and provides an efficient solution to obtain rapidly purified cadmium fractions (decontamination factors higher 100,000 for silver and palladium) which can directly be analyzed by multi collection inductively coupled plasma mass spectrometry (MC ICPMS). By applying the proposed procedure, accurate and precise cadmium isotope ratios were determined for the irradiated 109Ag transmutation target. [Copyright &y& Elsevier]
Copyright of Journal of Chromatography A is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 62844982
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PubTypeId: academicJournal
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  Data: Development of cadmium/silver/palladium separation by ion chromatography with quadrupole inductively coupled plasma mass spectrometry detection for off-line cadmium isotopic measurements
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  Data: <searchLink fieldCode="AR" term="%22Gautier%2C+C%2E%22">Gautier, C.</searchLink><i> celine.gautier@cea.fr</i><br /><searchLink fieldCode="AR" term="%22Bourgeois%2C+M%2E%22">Bourgeois, M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Isnard%2C+H%2E%22">Isnard, H.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Nonell%2C+A%2E%22">Nonell, A.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Stadelmann%2C+G%2E%22">Stadelmann, G.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Goutelard%2C+F%2E%22">Goutelard, F.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Chromatography+A%22">Journal of Chromatography A</searchLink>. Aug2011, Vol. 1218 Issue 31, p5241-5247. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Ion+exchange+chromatography%22">Ion exchange chromatography</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+partition%22">Phase partition</searchLink><br /><searchLink fieldCode="DE" term="%22Transition+metals%22">Transition metals</searchLink><br /><searchLink fieldCode="DE" term="%22Inductively+coupled+plasma+mass+spectrometry%22">Inductively coupled plasma mass spectrometry</searchLink><br /><searchLink fieldCode="DE" term="%22Cadmium+isotopes%22">Cadmium isotopes</searchLink><br /><searchLink fieldCode="DE" term="%22Carboxylic+acids%22">Carboxylic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Functional+groups%22">Functional groups</searchLink><br /><searchLink fieldCode="DE" term="%22Transmutation+%28Chemistry%29%22">Transmutation (Chemistry)</searchLink>
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  Data: Abstract: A separation method was investigated to perform off-line cadmium isotopic measurements on a 109Ag transmutation target. Ion chromatography (IC) with Q ICPMS detection (quadrupole inductively coupled plasma mass spectrometry detection) was chosen to separate cadmium from the isobarically interfering elements, silver and palladium, present in the sample. The optimization of chromatographic conditions was particularly studied. Several anion and cation columns (Dionex AG11®, CS10® and CS12®) were compared with different mobile phases (HNO3, HCl). The separation procedure was achieved with a carboxylate-functionalized cation exchange CS12 column using 0.5M HNO3 as eluent. The developed technique yielded satisfactory results in terms of separation factors (greater than 5) and provides an efficient solution to obtain rapidly purified cadmium fractions (decontamination factors higher 100,000 for silver and palladium) which can directly be analyzed by multi collection inductively coupled plasma mass spectrometry (MC ICPMS). By applying the proposed procedure, accurate and precise cadmium isotope ratios were determined for the irradiated 109Ag transmutation target. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of Journal of Chromatography A is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.chroma.2011.06.004
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Phase partition
        Type: general
      – SubjectFull: Transition metals
        Type: general
      – SubjectFull: Inductively coupled plasma mass spectrometry
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      – SubjectFull: Cadmium isotopes
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      – SubjectFull: Carboxylic acids
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      – SubjectFull: Functional groups
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      – SubjectFull: Transmutation (Chemistry)
        Type: general
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      – TitleFull: Development of cadmium/silver/palladium separation by ion chromatography with quadrupole inductively coupled plasma mass spectrometry detection for off-line cadmium isotopic measurements
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              Text: Aug2011
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              Y: 2011
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