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Transition metals supported on mesoporous ZrO2 for the catalytic control of indoor CO and PM emissions

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Title: Transition metals supported on mesoporous ZrO2 for the catalytic control of indoor CO and PM emissions
Authors: Doggali, Pradeep1, Waghmare, S.1, Rayalu, S.1, Teraoka, Y.2, Labhsetwar, Nitin1 nk_labhsetwar@neeri.res.in
Source: Journal of Molecular Catalysis A: Chemistry. Aug2011, Vol. 347 Issue 1/2, p52-59. 8p.
Subjects: Catalysis, Transition metals, Mesoporous materials, Zirconium oxide, Carbon monoxide, Biopolymers, Oxidation, Combustion
Abstract: Abstract: Mesoporous ZrO2 support has been prepared by using a low cost natural biopolymer chitosan as template, and different transition metals from the first row (Fe, Co, Ni, Cu and Mn) were impregnated on the synthesized support. The synthesized catalysts have been characterized by XRD, BET-SA, SEM, TEM, O2-TPD and TG analysis to study the material details as well as to understand the catalytic mechanism. The activity of these catalysts has been investigated for CO and PM oxidation. Incorporation of transition metals improved the activity for both CO and PM oxidation. It has been observed that Co–ZrO2 is the most active catalyst for studied reactions while, Ni based catalysts show the lowest activity for both the reactions. The transition metal supported catalysts follow the activity sequence Co–ZrO2 >Mn–ZrO2 >Cu–ZrO2 >Fe–ZrO2 >Ni–ZrO2. The effect of CO2, SO2 and H2O on CO oxidation activity was also investigated, and despite partial deactivation, the catalysts show good CO oxidation activity. The characterization of the materials by O2-TPD studies explains the better catalytic performance for the Co–ZrO2, Mn–ZrO2 and Cu–ZrO2 catalysts, as compared to Fe–ZrO2 and Ni–ZrO2. Such mesoporous zirconia with reasonably good surface area and without ordered structure could be useful for both CO and PM oxidation reactions. [Copyright &y& Elsevier]
Copyright of Journal of Molecular Catalysis A: Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 65047219
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Label: Title
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  Data: Transition metals supported on mesoporous ZrO<subscript>2</subscript> for the catalytic control of indoor CO and PM emissions
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  Data: <searchLink fieldCode="AR" term="%22Doggali%2C+Pradeep%22">Doggali, Pradeep</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Waghmare%2C+S%2E%22">Waghmare, S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Rayalu%2C+S%2E%22">Rayalu, S.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Teraoka%2C+Y%2E%22">Teraoka, Y.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Labhsetwar%2C+Nitin%22">Labhsetwar, Nitin</searchLink><relatesTo>1</relatesTo><i> nk_labhsetwar@neeri.res.in</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Molecular+Catalysis+A%3A+Chemistry%22">Journal of Molecular Catalysis A: Chemistry</searchLink>. Aug2011, Vol. 347 Issue 1/2, p52-59. 8p.
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  Data: <searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Transition+metals%22">Transition metals</searchLink><br /><searchLink fieldCode="DE" term="%22Mesoporous+materials%22">Mesoporous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Zirconium+oxide%22">Zirconium oxide</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon+monoxide%22">Carbon monoxide</searchLink><br /><searchLink fieldCode="DE" term="%22Biopolymers%22">Biopolymers</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation%22">Oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Combustion%22">Combustion</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Abstract: Mesoporous ZrO2 support has been prepared by using a low cost natural biopolymer chitosan as template, and different transition metals from the first row (Fe, Co, Ni, Cu and Mn) were impregnated on the synthesized support. The synthesized catalysts have been characterized by XRD, BET-SA, SEM, TEM, O2-TPD and TG analysis to study the material details as well as to understand the catalytic mechanism. The activity of these catalysts has been investigated for CO and PM oxidation. Incorporation of transition metals improved the activity for both CO and PM oxidation. It has been observed that Co–ZrO2 is the most active catalyst for studied reactions while, Ni based catalysts show the lowest activity for both the reactions. The transition metal supported catalysts follow the activity sequence Co–ZrO2 >Mn–ZrO2 >Cu–ZrO2 >Fe–ZrO2 >Ni–ZrO2. The effect of CO2, SO2 and H2O on CO oxidation activity was also investigated, and despite partial deactivation, the catalysts show good CO oxidation activity. The characterization of the materials by O2-TPD studies explains the better catalytic performance for the Co–ZrO2, Mn–ZrO2 and Cu–ZrO2 catalysts, as compared to Fe–ZrO2 and Ni–ZrO2. Such mesoporous zirconia with reasonably good surface area and without ordered structure could be useful for both CO and PM oxidation reactions. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Molecular Catalysis A: Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.molcata.2011.07.010
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      – Code: eng
        Text: English
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        PageCount: 8
        StartPage: 52
    Subjects:
      – SubjectFull: Catalysis
        Type: general
      – SubjectFull: Transition metals
        Type: general
      – SubjectFull: Mesoporous materials
        Type: general
      – SubjectFull: Zirconium oxide
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      – SubjectFull: Carbon monoxide
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      – SubjectFull: Biopolymers
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      – SubjectFull: Oxidation
        Type: general
      – SubjectFull: Combustion
        Type: general
    Titles:
      – TitleFull: Transition metals supported on mesoporous ZrO2 for the catalytic control of indoor CO and PM emissions
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            NameFull: Doggali, Pradeep
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            NameFull: Waghmare, S.
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            NameFull: Rayalu, S.
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            NameFull: Teraoka, Y.
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            NameFull: Labhsetwar, Nitin
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              M: 08
              Text: Aug2011
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              Y: 2011
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              Value: 347
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            – TitleFull: Journal of Molecular Catalysis A: Chemistry
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