Critical phenomena and estimation of the spontaneous magnetization through magnetic entropy change in La0.67Ba0.33Mn0.98Ti0.02O3

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Title: Critical phenomena and estimation of the spontaneous magnetization through magnetic entropy change in La0.67Ba0.33Mn0.98Ti0.02O3
Authors: Oumezzine, Marwène1 oumezzine@hotmail.co.uk, Peña, Octavio2, Kallel, Sami1, Zemni, Sadok1
Source: Solid State Sciences. Oct2011, Vol. 13 Issue 10, p1829-1834. 6p.
Subjects: Lanthanum compounds, Estimation theory, Magnetization, Entropy, Perovskite, Critical phenomena (Physics), Manganite
Abstract: Abstract: The critical properties of the manganese perovskite La0.67Ba0.33Mn0.98Ti0.02O3 around the paramagnetic-ferromagnetic phase transition were investigated through various techniques such as modified Arrott plot, Kouvel–Fisher method and critical isotherm analysis based on the data of static magnetic measurements recorded around the Curie temperature T c. The magnetic data analyzed in the critical region using the above methods yield the critical exponents β =0.551±0.008 with T c =310.47K±0.10 (from the temperature dependence of the spontaneous magnetization below T C) and γ =1.020±0.024 with T C =310.11K±0.14 (from the temperature dependence of the inverse initial susceptibility above T C) and δ =2.826, determined separately from the isothermal magnetization at T C. These critical exponents fulfill the Widom scaling relation δ =1+ γ/β, implying that the obtained values of β and γ are reliable. Based on these critical exponents, the magnetization–field–temperature (M–H–T) data around T c collapse into two curves obeying the single scaling equation . The values deduced for the critical exponents in La0.67Ba0.33Mn0.98Ti0.02O3 are close to the theoretical prediction of the mean-field model rather than the universal theory of 3D-Heisenberg, 3D-Ising and tricritical mean-field models. Moreover we have investigated the validity and usefulness of the theoretical modeling in our compound La0.67Ba0.33Mn0.98Ti0.02O3 based on the mean-field analysis of the magnetic entropy change (‑∆S M) versus the magnetization data. Results obtained through this approach are compared to those obtained from extrapolation of the Arrott curves. An excellent agreement was obtained between this approach with the one obtained from the extrapolation of the Arrott curves. [Copyright &y& Elsevier]
Copyright of Solid State Sciences is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Abstract: The critical properties of the manganese perovskite La0.67Ba0.33Mn0.98Ti0.02O3 around the paramagnetic-ferromagnetic phase transition were investigated through various techniques such as modified Arrott plot, Kouvel–Fisher method and critical isotherm analysis based on the data of static magnetic measurements recorded around the Curie temperature T c. The magnetic data analyzed in the critical region using the above methods yield the critical exponents β =0.551±0.008 with T c =310.47K±0.10 (from the temperature dependence of the spontaneous magnetization below T C) and γ =1.020±0.024 with T C =310.11K±0.14 (from the temperature dependence of the inverse initial susceptibility above T C) and δ =2.826, determined separately from the isothermal magnetization at T C. These critical exponents fulfill the Widom scaling relation δ =1+ γ/β, implying that the obtained values of β and γ are reliable. Based on these critical exponents, the magnetization–field–temperature (M–H–T) data around T c collapse into two curves obeying the single scaling equation . The values deduced for the critical exponents in La0.67Ba0.33Mn0.98Ti0.02O3 are close to the theoretical prediction of the mean-field model rather than the universal theory of 3D-Heisenberg, 3D-Ising and tricritical mean-field models. Moreover we have investigated the validity and usefulness of the theoretical modeling in our compound La0.67Ba0.33Mn0.98Ti0.02O3 based on the mean-field analysis of the magnetic entropy change (‑∆S M) versus the magnetization data. Results obtained through this approach are compared to those obtained from extrapolation of the Arrott curves. An excellent agreement was obtained between this approach with the one obtained from the extrapolation of the Arrott curves. [Copyright &y& Elsevier]
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  Label:
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  Data: <i>Copyright of Solid State Sciences is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.solidstatesciences.2011.07.019
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 6
        StartPage: 1829
    Subjects:
      – SubjectFull: Lanthanum compounds
        Type: general
      – SubjectFull: Estimation theory
        Type: general
      – SubjectFull: Magnetization
        Type: general
      – SubjectFull: Entropy
        Type: general
      – SubjectFull: Perovskite
        Type: general
      – SubjectFull: Critical phenomena (Physics)
        Type: general
      – SubjectFull: Manganite
        Type: general
    Titles:
      – TitleFull: Critical phenomena and estimation of the spontaneous magnetization through magnetic entropy change in La0.67Ba0.33Mn0.98Ti0.02O3
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            NameFull: Oumezzine, Marwène
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            NameFull: Peña, Octavio
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            NameFull: Kallel, Sami
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            NameFull: Zemni, Sadok
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              M: 10
              Text: Oct2011
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              Y: 2011
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