View in EDS

Effect of oxygenation time on signal of a sensor based on ionic liquids

Saved in:
Bibliographic Details
Title: Effect of oxygenation time on signal of a sensor based on ionic liquids
Authors: Gębicki, Jacek1 jacek.gebicki@pg.gda.pl, Kloskowski, Adam2, Chrzanowski, Wojciech2
Source: Electrochimica Acta. Nov2011, Vol. 56 Issue 27, p9910-9915. 6p.
Subjects: Ionic liquids, Oxygen, Chemical detectors, Electrodes, Volumetric analysis, Analytical chemistry, Oxidation-reduction reaction, Reaction mechanisms (Chemistry)
Abstract: Abstract: The paper presents an oxygen sensor based on ionic liquids and solid electrodes. The following ionic liquids have been employed: [BMIM][BF4], [HMIM][Cl], [BMIM][N(CN2)]. Minimum time of the sensor exposure to analyte, after which the signal (current intensity) was stable, has been evaluated. An impact of volumetric flow rate of analyte on the sensor exposure time and signal has been determined. A product of permeability coefficient and solubility of oxygen in ionic liquids has been estimated. A mechanism of oxygen reduction on a surface of the solid electrodes, in the ionic liquid environment has been presented. Overall cathodic coefficients of transition for the sensors with particular ionic liquids have been determined as a function of potential scan rate. [Copyright &y& Elsevier]
Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 66854341
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Effect of oxygenation time on signal of a sensor based on ionic liquids
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Gębicki%2C+Jacek%22">Gębicki, Jacek</searchLink><relatesTo>1</relatesTo><i> jacek.gebicki@pg.gda.pl</i><br /><searchLink fieldCode="AR" term="%22Kloskowski%2C+Adam%22">Kloskowski, Adam</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Chrzanowski%2C+Wojciech%22">Chrzanowski, Wojciech</searchLink><relatesTo>2</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Electrochimica+Acta%22">Electrochimica Acta</searchLink>. Nov2011, Vol. 56 Issue 27, p9910-9915. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Ionic+liquids%22">Ionic liquids</searchLink><br /><searchLink fieldCode="DE" term="%22Oxygen%22">Oxygen</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+detectors%22">Chemical detectors</searchLink><br /><searchLink fieldCode="DE" term="%22Electrodes%22">Electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Volumetric+analysis%22">Volumetric analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Analytical+chemistry%22">Analytical chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation-reduction+reaction%22">Oxidation-reduction reaction</searchLink><br /><searchLink fieldCode="DE" term="%22Reaction+mechanisms+%28Chemistry%29%22">Reaction mechanisms (Chemistry)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: The paper presents an oxygen sensor based on ionic liquids and solid electrodes. The following ionic liquids have been employed: [BMIM][BF4], [HMIM][Cl], [BMIM][N(CN2)]. Minimum time of the sensor exposure to analyte, after which the signal (current intensity) was stable, has been evaluated. An impact of volumetric flow rate of analyte on the sensor exposure time and signal has been determined. A product of permeability coefficient and solubility of oxygen in ionic liquids has been estimated. A mechanism of oxygen reduction on a surface of the solid electrodes, in the ionic liquid environment has been presented. Overall cathodic coefficients of transition for the sensors with particular ionic liquids have been determined as a function of potential scan rate. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=66854341
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.electacta.2011.08.059
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 9910
    Subjects:
      – SubjectFull: Ionic liquids
        Type: general
      – SubjectFull: Oxygen
        Type: general
      – SubjectFull: Chemical detectors
        Type: general
      – SubjectFull: Electrodes
        Type: general
      – SubjectFull: Volumetric analysis
        Type: general
      – SubjectFull: Analytical chemistry
        Type: general
      – SubjectFull: Oxidation-reduction reaction
        Type: general
      – SubjectFull: Reaction mechanisms (Chemistry)
        Type: general
    Titles:
      – TitleFull: Effect of oxygenation time on signal of a sensor based on ionic liquids
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Gębicki, Jacek
      – PersonEntity:
          Name:
            NameFull: Kloskowski, Adam
      – PersonEntity:
          Name:
            NameFull: Chrzanowski, Wojciech
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 30
              M: 11
              Text: Nov2011
              Type: published
              Y: 2011
          Identifiers:
            – Type: issn-print
              Value: 00134686
          Numbering:
            – Type: volume
              Value: 56
            – Type: issue
              Value: 27
          Titles:
            – TitleFull: Electrochimica Acta
              Type: main
ResultId 1