Reverse saturable absorption in chlorophyll A solutions.

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Title: Reverse saturable absorption in chlorophyll A solutions.
Authors: Corrêa, D.S., De Boni, L., dos Santos Jr., D.S., Barbosa Neto, N.M., Oliveira Jr., O.N., Misoguti, L., Zilio, S.C., Mendonça, C.R.
Source: Applied Physics B: Lasers & Optics. 2002, Vol. 74 Issue 6, p559. 3p.
Subjects: Chlorophyll, Chloroform
Abstract: The dynamic nonlinear absorption of a chloroform solution of chlorophyll A was investigated using the Z-scan technique with picosecond pulses at 532 nm. The nonlinear absorption exhibits a reverse saturation, indicating a strong intersystem crossing (singlet–triplet) process. The time evolution of the optical nonlinearity, modeled by means of a five-level energy diagram, allows the determination of excited-state cross sections and the lifetime of the intersystem crossing based on its absorption characteristics and efficient formation of triplet states. Chlorophyll A was found to be a good candidate for a sensitizer in photodynamic therapy. [ABSTRACT FROM AUTHOR]
Copyright of Applied Physics B: Lasers & Optics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: <searchLink fieldCode="JN" term="%22Applied+Physics+B%3A+Lasers+%26+Optics%22">Applied Physics B: Lasers & Optics</searchLink>. 2002, Vol. 74 Issue 6, p559. 3p.
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  Data: <searchLink fieldCode="DE" term="%22Chlorophyll%22">Chlorophyll</searchLink><br /><searchLink fieldCode="DE" term="%22Chloroform%22">Chloroform</searchLink>
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  Data: The dynamic nonlinear absorption of a chloroform solution of chlorophyll A was investigated using the Z-scan technique with picosecond pulses at 532 nm. The nonlinear absorption exhibits a reverse saturation, indicating a strong intersystem crossing (singlet–triplet) process. The time evolution of the optical nonlinearity, modeled by means of a five-level energy diagram, allows the determination of excited-state cross sections and the lifetime of the intersystem crossing based on its absorption characteristics and efficient formation of triplet states. Chlorophyll A was found to be a good candidate for a sensitizer in photodynamic therapy. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Applied Physics B: Lasers & Optics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Text: English
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      – SubjectFull: Chlorophyll
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      – SubjectFull: Chloroform
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            NameFull: Zilio, S.C.
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              Text: 2002
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