Crystal Structure of the Cubic Modification of Cu[sub 2]FeSnS[sub 4].
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| Title: | Crystal Structure of the Cubic Modification of Cu[sub 2]FeSnS[sub 4]. |
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| Authors: | Evstigneeva, T. L., Kabalov, Yu. K. |
| Source: | Crystallography Reports. May2001, Vol. 46 Issue 3, p368. 5p. |
| Subjects: | Crystallography, Stannite |
| Abstract: | The structure of Cu[sub 2-x]Fe[sub 1-x]SnS[sub 4], the last member of the isomorphous series Cu[sub 3]FeS[sub 4-] Cu[sub 2]FeSnS[sub 4], was synthesized for the first time and solved by the Rietveld method (the WYRIET 3.3 version). The compound occurs as a cubic phase (a[sub 0] = 5.4179(5) Å) crystallizing in the sp. gr. P&4macr;3m. One-half of the tetrahedral cavities in the close packing of sulfur atoms [4e (xxx), x = 0.2583(5)] are statistically filled with metal atoms (Sn + Fe) and (Cu + Fe + Sn) [la (0 0 0) and 3c (0 1/2 1/2), respectively]. The results of X-ray study (R[sub p] = 2.33, R[sub wp] = 3.00, s = 1.20, D = 1.53, R[sub B] = 2.52, and R[sub F] = 2.00) confirm the existence of the stannite "prototype" with a "small" cubic unit cell. [ABSTRACT FROM AUTHOR] |
| Copyright of Crystallography Reports is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
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| Items | – Name: Title Label: Title Group: Ti Data: Crystal Structure of the Cubic Modification of Cu[sub 2]FeSnS[sub 4]. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Evstigneeva%2C+T%2E+L%2E%22">Evstigneeva, T. L.</searchLink><br /><searchLink fieldCode="AR" term="%22Kabalov%2C+Yu%2E+K%2E%22">Kabalov, Yu. K.</searchLink> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Crystallography+Reports%22">Crystallography Reports</searchLink>. May2001, Vol. 46 Issue 3, p368. 5p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Crystallography%22">Crystallography</searchLink><br /><searchLink fieldCode="DE" term="%22Stannite%22">Stannite</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The structure of Cu[sub 2-x]Fe[sub 1-x]SnS[sub 4], the last member of the isomorphous series Cu[sub 3]FeS[sub 4-] Cu[sub 2]FeSnS[sub 4], was synthesized for the first time and solved by the Rietveld method (the WYRIET 3.3 version). The compound occurs as a cubic phase (a[sub 0] = 5.4179(5) Å) crystallizing in the sp. gr. P&4macr;3m. One-half of the tetrahedral cavities in the close packing of sulfur atoms [4e (xxx), x = 0.2583(5)] are statistically filled with metal atoms (Sn + Fe) and (Cu + Fe + Sn) [la (0 0 0) and 3c (0 1/2 1/2), respectively]. The results of X-ray study (R[sub p] = 2.33, R[sub wp] = 3.00, s = 1.20, D = 1.53, R[sub B] = 2.52, and R[sub F] = 2.00) confirm the existence of the stannite "prototype" with a "small" cubic unit cell. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Crystallography Reports is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1134/1.1376461 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 5 StartPage: 368 Subjects: – SubjectFull: Crystallography Type: general – SubjectFull: Stannite Type: general Titles: – TitleFull: Crystal Structure of the Cubic Modification of Cu[sub 2]FeSnS[sub 4]. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Evstigneeva, T. L. – PersonEntity: Name: NameFull: Kabalov, Yu. K. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 05 Text: May2001 Type: published Y: 2001 Identifiers: – Type: issn-print Value: 10637745 Numbering: – Type: volume Value: 46 – Type: issue Value: 3 Titles: – TitleFull: Crystallography Reports Type: main |
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