Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC

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Title: Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC
Authors: Bozza, F.1 frbo@risoe.dtu.dk, Schafbauer, W.2, Meulenberg, W.A.2, Bonanos, N.1
Source: International Journal of Hydrogen Energy. May2012, Vol. 37 Issue 9, p8027-8032. 6p.
Subjects: Lanthanum compounds, Anodes, Nickel electrodes, Electrophoretic deposition, Electrolytes, Sintering, Performance evaluation
Abstract: Abstract: The Electrophoretic Deposition (EPD) technique has been applied to the preparation of a porous La0.995Ca0.005NbO4/Ni composite anode layer, deposited on a porous pre-sintered La0.995Ca0.005NbO4/Ni support. Powders of La0.995Ca0.005NbO4 and NiO were suspended in a solution of acetylacetone, iodine and water. Selectivity in the composition of the deposited layer was analyzed as a function of the suspension compositions and deposition conditions. A quasi-symmetrical cell was produced by depositing La0.995Ca0.005NbO4 electrolyte layer on the anode layer by EPD, and by applying a porous La0.995Ca0.005NbO4/Ni counter electrode on the dense electrolyte layer by brushing. The performance of the electrodes was evaluated by electrochemical impedance spectroscopy in 3% wet H2. [Copyright &y& Elsevier]
Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Characterization of La<subscript>0.995</subscript>Ca<subscript>0.005</subscript>NbO<subscript>4</subscript>/Ni anode functional layer by electrophoretic deposition in a La<subscript>0.995</subscript>Ca<subscript>0.005</subscript>NbO<subscript>4</subscript> electrolyte based PCFC
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Hydrogen+Energy%22">International Journal of Hydrogen Energy</searchLink>. May2012, Vol. 37 Issue 9, p8027-8032. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Lanthanum+compounds%22">Lanthanum compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Anodes%22">Anodes</searchLink><br /><searchLink fieldCode="DE" term="%22Nickel+electrodes%22">Nickel electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Electrophoretic+deposition%22">Electrophoretic deposition</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolytes%22">Electrolytes</searchLink><br /><searchLink fieldCode="DE" term="%22Sintering%22">Sintering</searchLink><br /><searchLink fieldCode="DE" term="%22Performance+evaluation%22">Performance evaluation</searchLink>
– Name: Abstract
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  Data: Abstract: The Electrophoretic Deposition (EPD) technique has been applied to the preparation of a porous La0.995Ca0.005NbO4/Ni composite anode layer, deposited on a porous pre-sintered La0.995Ca0.005NbO4/Ni support. Powders of La0.995Ca0.005NbO4 and NiO were suspended in a solution of acetylacetone, iodine and water. Selectivity in the composition of the deposited layer was analyzed as a function of the suspension compositions and deposition conditions. A quasi-symmetrical cell was produced by depositing La0.995Ca0.005NbO4 electrolyte layer on the anode layer by EPD, and by applying a porous La0.995Ca0.005NbO4/Ni counter electrode on the dense electrolyte layer by brushing. The performance of the electrodes was evaluated by electrochemical impedance spectroscopy in 3% wet H2. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.ijhydene.2011.11.002
    Languages:
      – Code: eng
        Text: English
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        PageCount: 6
        StartPage: 8027
    Subjects:
      – SubjectFull: Lanthanum compounds
        Type: general
      – SubjectFull: Anodes
        Type: general
      – SubjectFull: Nickel electrodes
        Type: general
      – SubjectFull: Electrophoretic deposition
        Type: general
      – SubjectFull: Electrolytes
        Type: general
      – SubjectFull: Sintering
        Type: general
      – SubjectFull: Performance evaluation
        Type: general
    Titles:
      – TitleFull: Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC
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            NameFull: Bozza, F.
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            NameFull: Schafbauer, W.
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            NameFull: Meulenberg, W.A.
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            NameFull: Bonanos, N.
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            – D: 01
              M: 05
              Text: May2012
              Type: published
              Y: 2012
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