Effects of copper nanowires on the properties of an organic phase change material

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Title: Effects of copper nanowires on the properties of an organic phase change material
Authors: Zeng, Ju-Lan1 julan_zeng@yahoo.com.cn, Zhu, Fu-Rong1, Yu, Sai-Bo2, Zhu, Ling1, Cao, Zhong1, Sun, Li-Xian1, Deng, Guang-Rong1, Yan, Wen-Pei1, Zhang, Ling1
Source: Solar Energy Materials & Solar Cells. Oct2012, p174-178. 5p.
Subjects: Physiological effects of copper, Nanowires, Phase change materials, Microstructure, Thermal conductivity of metals, Metal clusters
Abstract: Abstract: The effects of copper nanowires (Cu NWs) with ultra-high aspect ratio and sponge-like structure on the properties of an organic phase change material (PCM) were investigated. Tetradecanol (TD) was selected as the organic PCM. The sponge-like Cu NWs clusters were randomly dispersed in the TD matrix and were wrapped by TD to form a new kind of composite PCM. The phase change enthalpy (ΔH) of the composite PCMs was decreased linearly with the increasing of Cu NWs loading, while the melting speed was accelerated. The thermal conductivity of the composite PCMs was greatly enhanced by Cu NWs. The ΔH of the composite PCM containing 58.9wt% (corresponding to 11.9vol%) of Cu NWs was 86.95J/g, and the thermal conductivity attained to 2.86W/mK, which was nearly 9 times higher than that of the TD. The thermal conductivity enhancement of Cu NWs on the composite PCMs showed a turning point at the Cu NWs loading of 1.5vol%. When Cu NWs loading exceeded 1.5vol%, the thermal conductivity of the composite PCMs increased significantly faster with the increasing of Cu NWs loading. [Copyright &y& Elsevier]
Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Effects of copper nanowires on the properties of an organic phase change material
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  Data: <searchLink fieldCode="AR" term="%22Zeng%2C+Ju-Lan%22">Zeng, Ju-Lan</searchLink><relatesTo>1</relatesTo><i> julan_zeng@yahoo.com.cn</i><br /><searchLink fieldCode="AR" term="%22Zhu%2C+Fu-Rong%22">Zhu, Fu-Rong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yu%2C+Sai-Bo%22">Yu, Sai-Bo</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhu%2C+Ling%22">Zhu, Ling</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Cao%2C+Zhong%22">Cao, Zhong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Sun%2C+Li-Xian%22">Sun, Li-Xian</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Deng%2C+Guang-Rong%22">Deng, Guang-Rong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yan%2C+Wen-Pei%22">Yan, Wen-Pei</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhang%2C+Ling%22">Zhang, Ling</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Solar+Energy+Materials+%26+Solar+Cells%22">Solar Energy Materials & Solar Cells</searchLink>. Oct2012, p174-178. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Physiological+effects+of+copper%22">Physiological effects of copper</searchLink><br /><searchLink fieldCode="DE" term="%22Nanowires%22">Nanowires</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+change+materials%22">Phase change materials</searchLink><br /><searchLink fieldCode="DE" term="%22Microstructure%22">Microstructure</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+conductivity+of+metals%22">Thermal conductivity of metals</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+clusters%22">Metal clusters</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: Abstract: The effects of copper nanowires (Cu NWs) with ultra-high aspect ratio and sponge-like structure on the properties of an organic phase change material (PCM) were investigated. Tetradecanol (TD) was selected as the organic PCM. The sponge-like Cu NWs clusters were randomly dispersed in the TD matrix and were wrapped by TD to form a new kind of composite PCM. The phase change enthalpy (ΔH) of the composite PCMs was decreased linearly with the increasing of Cu NWs loading, while the melting speed was accelerated. The thermal conductivity of the composite PCMs was greatly enhanced by Cu NWs. The ΔH of the composite PCM containing 58.9wt% (corresponding to 11.9vol%) of Cu NWs was 86.95J/g, and the thermal conductivity attained to 2.86W/mK, which was nearly 9 times higher than that of the TD. The thermal conductivity enhancement of Cu NWs on the composite PCMs showed a turning point at the Cu NWs loading of 1.5vol%. When Cu NWs loading exceeded 1.5vol%, the thermal conductivity of the composite PCMs increased significantly faster with the increasing of Cu NWs loading. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Solar Energy Materials & Solar Cells is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.solmat.2012.06.013
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 5
        StartPage: 174
    Subjects:
      – SubjectFull: Physiological effects of copper
        Type: general
      – SubjectFull: Nanowires
        Type: general
      – SubjectFull: Phase change materials
        Type: general
      – SubjectFull: Microstructure
        Type: general
      – SubjectFull: Thermal conductivity of metals
        Type: general
      – SubjectFull: Metal clusters
        Type: general
    Titles:
      – TitleFull: Effects of copper nanowires on the properties of an organic phase change material
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            NameFull: Zeng, Ju-Lan
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            NameFull: Zhu, Fu-Rong
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            NameFull: Yu, Sai-Bo
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            NameFull: Zhu, Ling
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            NameFull: Cao, Zhong
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            NameFull: Yan, Wen-Pei
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          Dates:
            – D: 01
              M: 10
              Text: Oct2012
              Type: published
              Y: 2012
          Identifiers:
            – Type: issn-print
              Value: 09270248
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            – TitleFull: Solar Energy Materials & Solar Cells
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