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Studies on solution-grown pure and doped Sodium Potassium tartrate crystals

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Title: Studies on solution-grown pure and doped Sodium Potassium tartrate crystals
Authors: Mathivanan, V.1,2 mr.mathivanan@rediffmail.com, Haris, M.1
Source: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Feb2013, Vol. 102, p341-349. 9p.
Subjects: Solution (Chemistry), Doping agents (Chemistry), Sodium compounds, Potassium, Oscillating chemical reactions, Salt crystals, Rochelle salt
Abstract: Abstract: A systematic analysis of the Fourier transform infrared spectroscopy and Raman spectra of pure and Cu(NO3)23H2O doped Rochelle salt (NaKC4H4O64H2O) in terms of the standard frequency correlations, deuteration shift and typical nature (with respect to intensity and width) of bands due to different modes is reported. The bands due to the internal modes (excluding some skeletal modes) of the ion appear as doublets. For certain modes (e.g. β CH, γ C(OH) and δ COO) doublets arise owing to interaction between two identical oscillations of two identical groups in COO(HO)HCCH(OH)COO2−, while for other modes (e.g. γ CH, , , δ COH and τ COO) they arise owing to crystallographically distinguishable sites for two identical oscillators. The effect of dopant in the pure Rochelle salt crystals is found out by using Elemental analysis. The unit cell volume of pure and Cu(NO3)23H2O doped Rochelle salt crystals is found out from powder X-ray diffraction studies. [Copyright &y& Elsevier]
Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 84598485
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PubTypeId: academicJournal
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  Data: Studies on solution-grown pure and doped Sodium Potassium tartrate crystals
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  Data: <searchLink fieldCode="AR" term="%22Mathivanan%2C+V%2E%22">Mathivanan, V.</searchLink><relatesTo>1,2</relatesTo><i> mr.mathivanan@rediffmail.com</i><br /><searchLink fieldCode="AR" term="%22Haris%2C+M%2E%22">Haris, M.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Spectrochimica+Acta+Part+A%3A+Molecular+%26+Biomolecular+Spectroscopy%22">Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy</searchLink>. Feb2013, Vol. 102, p341-349. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Solution+%28Chemistry%29%22">Solution (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Doping+agents+%28Chemistry%29%22">Doping agents (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Sodium+compounds%22">Sodium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Potassium%22">Potassium</searchLink><br /><searchLink fieldCode="DE" term="%22Oscillating+chemical+reactions%22">Oscillating chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Salt+crystals%22">Salt crystals</searchLink><br /><searchLink fieldCode="DE" term="%22Rochelle+salt%22">Rochelle salt</searchLink>
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  Data: Abstract: A systematic analysis of the Fourier transform infrared spectroscopy and Raman spectra of pure and Cu(NO3)23H2O doped Rochelle salt (NaKC4H4O64H2O) in terms of the standard frequency correlations, deuteration shift and typical nature (with respect to intensity and width) of bands due to different modes is reported. The bands due to the internal modes (excluding some skeletal modes) of the ion appear as doublets. For certain modes (e.g. β CH, γ C(OH) and δ COO) doublets arise owing to interaction between two identical oscillations of two identical groups in COO(HO)HCCH(OH)COO2−, while for other modes (e.g. γ CH, , , δ COH and τ COO) they arise owing to crystallographically distinguishable sites for two identical oscillators. The effect of dopant in the pure Rochelle salt crystals is found out by using Elemental analysis. The unit cell volume of pure and Cu(NO3)23H2O doped Rochelle salt crystals is found out from powder X-ray diffraction studies. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1016/j.saa.2012.10.033
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: 341
    Subjects:
      – SubjectFull: Solution (Chemistry)
        Type: general
      – SubjectFull: Doping agents (Chemistry)
        Type: general
      – SubjectFull: Sodium compounds
        Type: general
      – SubjectFull: Potassium
        Type: general
      – SubjectFull: Oscillating chemical reactions
        Type: general
      – SubjectFull: Salt crystals
        Type: general
      – SubjectFull: Rochelle salt
        Type: general
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      – TitleFull: Studies on solution-grown pure and doped Sodium Potassium tartrate crystals
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            NameFull: Haris, M.
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            – D: 01
              M: 02
              Text: Feb2013
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              Y: 2013
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            – TitleFull: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy
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