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Water-Insoluble Heterometal-Oxide-Based PhotocatalystsEffective for the Photo-Decomposition of Methyl Orange.

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Title: Water-Insoluble Heterometal-Oxide-Based PhotocatalystsEffective for the Photo-Decomposition of Methyl Orange.
Authors: Chen, Yong-Qiang1, Li, Guo-Rong1, Qu, Yang-Kun1, Zhang, Ying-Hui1, He, Kun-Huan1, Gao, Qiang1, Bu, Xian-He1
Source: Crystal Growth & Design. Feb2013, Vol. 13 Issue 2, p901-907. 7p.
Subjects: Water chemistry, Metallic oxides, Photocatalysis, Chemical decomposition, Methyl groups, Metal ions
Abstract: Two water-insoluble isostructural inorganic–organichybridmaterials, [M(pytpy)2Mo4O13]∞(M = Cu 1, Ni 2, pytpy =4′-(4-pyridyl)-4,2′:6′,4″-terpyridine),have been prepared by in situformation of the Mo4O132–clusters from the decompositionof H3PMo12under hydrothermal conditions. Bothof the two complexes display three-dimensional (3D) “pillar-layer”frameworks based on bimetal-oxide layers pillared by the pytpy ligands.Topological analysis revealed that two 3D frameworks can be simplifiedinto (3,4,4)-connected (42.62.83)2(4.62)2(44.102) and (3,5,6)-connected (42.6)2(44.66)2(44.68.83) topologies with the metal ions as nodes, respectively. Importantly,good photocatalytic activities were observed for both complexes inthe photodecomposition of methyl orange (MO) solution under UV lightirradiation. [ABSTRACT FROM AUTHOR]
Copyright of Crystal Growth & Design is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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An: 85342288
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  Label: Title
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  Data: Water-Insoluble Heterometal-Oxide-Based PhotocatalystsEffective for the Photo-Decomposition of Methyl Orange.
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  Data: <searchLink fieldCode="AR" term="%22Chen%2C+Yong-Qiang%22">Chen, Yong-Qiang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Li%2C+Guo-Rong%22">Li, Guo-Rong</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Qu%2C+Yang-Kun%22">Qu, Yang-Kun</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zhang%2C+Ying-Hui%22">Zhang, Ying-Hui</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22He%2C+Kun-Huan%22">He, Kun-Huan</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Gao%2C+Qiang%22">Gao, Qiang</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Bu%2C+Xian-He%22">Bu, Xian-He</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Crystal+Growth+%26+Design%22">Crystal Growth & Design</searchLink>. Feb2013, Vol. 13 Issue 2, p901-907. 7p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Water+chemistry%22">Water chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+oxides%22">Metallic oxides</searchLink><br /><searchLink fieldCode="DE" term="%22Photocatalysis%22">Photocatalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+decomposition%22">Chemical decomposition</searchLink><br /><searchLink fieldCode="DE" term="%22Methyl+groups%22">Methyl groups</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+ions%22">Metal ions</searchLink>
– Name: Abstract
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  Data: Two water-insoluble isostructural inorganic–organichybridmaterials, [M(pytpy)2Mo4O13]∞(M = Cu 1, Ni 2, pytpy =4′-(4-pyridyl)-4,2′:6′,4″-terpyridine),have been prepared by in situformation of the Mo4O132–clusters from the decompositionof H3PMo12under hydrothermal conditions. Bothof the two complexes display three-dimensional (3D) “pillar-layer”frameworks based on bimetal-oxide layers pillared by the pytpy ligands.Topological analysis revealed that two 3D frameworks can be simplifiedinto (3,4,4)-connected (42.62.83)2(4.62)2(44.102) and (3,5,6)-connected (42.6)2(44.66)2(44.68.83) topologies with the metal ions as nodes, respectively. Importantly,good photocatalytic activities were observed for both complexes inthe photodecomposition of methyl orange (MO) solution under UV lightirradiation. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Crystal Growth & Design is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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        Value: 10.1021/cg3016244
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      – Code: eng
        Text: English
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        PageCount: 7
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        Type: general
      – SubjectFull: Metallic oxides
        Type: general
      – SubjectFull: Photocatalysis
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      – SubjectFull: Chemical decomposition
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      – SubjectFull: Methyl groups
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      – SubjectFull: Metal ions
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      – TitleFull: Water-Insoluble Heterometal-Oxide-Based PhotocatalystsEffective for the Photo-Decomposition of Methyl Orange.
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              Text: Feb2013
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              Y: 2013
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