Cu2ZnSnS4 thin films grown by flash evaporation and subsequent annealing in Ar atmosphere

Saved in:
Bibliographic Details
Title: Cu2ZnSnS4 thin films grown by flash evaporation and subsequent annealing in Ar atmosphere
Authors: Caballero, R.1 raquel.caballero@uam.es, Izquierdo-Roca, V.2, Merino, J.M.1, Friedrich, E.J.1, Climent-Font, A.1,3, Saucedo, E.2, Pérez-Rodríguez, A.2,4, León, M.1
Source: Thin Solid Films. May2013, Vol. 535, p62-66. 5p.
Subjects: Kesterite, Thin films, Crystal growth, Flash distillation process in saline water conversion, Annealing of metals, Argon, Stoichiometry, Raman spectroscopy
Abstract: Abstract: A study of Cu2ZnSnS4 thin films grown by flash evaporation and subsequently annealed in Ar atmosphere has been carried out. Prior to thin film deposition, Cu2ZnSnS4 bulk compounds with stoichiometric and Zn-rich compositions were synthesized as evaporation sources. The characteristics of the bulk compounds and thin films were investigated by X-ray diffraction, Raman spectroscopy, scanning electron microscopy and elastic back scattering. Cu2ZnSnS4 deposited films contain lower concentrations of Zn than the bulk compounds used as evaporation sources, which is related to a preferential Zn re-evaporation during the deposition process. The desired kesterite composition for solar cell applications was achieved by using a Zn-rich compound as the evaporation source plus a thermal treatment at 620°C in Ar atmosphere. [Copyright &y& Elsevier]
Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Description
Abstract:Abstract: A study of Cu2ZnSnS4 thin films grown by flash evaporation and subsequently annealed in Ar atmosphere has been carried out. Prior to thin film deposition, Cu2ZnSnS4 bulk compounds with stoichiometric and Zn-rich compositions were synthesized as evaporation sources. The characteristics of the bulk compounds and thin films were investigated by X-ray diffraction, Raman spectroscopy, scanning electron microscopy and elastic back scattering. Cu2ZnSnS4 deposited films contain lower concentrations of Zn than the bulk compounds used as evaporation sources, which is related to a preferential Zn re-evaporation during the deposition process. The desired kesterite composition for solar cell applications was achieved by using a Zn-rich compound as the evaporation source plus a thermal treatment at 620°C in Ar atmosphere. [Copyright &y& Elsevier]
ISSN:00406090
DOI:10.1016/j.tsf.2012.10.028