Bibliographic Details
| Title: |
Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P → B Interactions. |
| Authors: |
Bontemps, Sébastien1, Devillard, Marc1, Mallet-Ladeira, Sonia2, Bouhadir, Ghenwa1, Miqueu, Karinne3 karinne.miqueu@univ-pau.fr, Bourissou, Didier1 dbouriss@chimie.ups-tlse.fr |
| Source: |
Inorganic Chemistry. 4/15/2013, Vol. 52 Issue 8, p4714-4720. 7p. |
| Subjects: |
Naphthalene, Lewis acids, Phosphine derivatives, Electronic structure, Boron, Crystallography |
| Abstract: |
Three naphtha-bridged phosphine-borane derivatives 2-BCy2, 2-BMes2, and 2-BFlu, differing in the steric and electronic properties of the boryl moiety, have been prepared and characterized by spectroscopic and crystallographic means. The presence and magnitude of the P → B interactions have been assessed experimentally and theoretically. The naphdiyl linker was found to enforce the P → B interaction despite steric shielding, while retaining enough flexibility to respond to the Lewis acidity of boron. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
