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Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P → B Interactions.

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Title: Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P → B Interactions.
Authors: Bontemps, Sébastien1, Devillard, Marc1, Mallet-Ladeira, Sonia2, Bouhadir, Ghenwa1, Miqueu, Karinne3 karinne.miqueu@univ-pau.fr, Bourissou, Didier1 dbouriss@chimie.ups-tlse.fr
Source: Inorganic Chemistry. 4/15/2013, Vol. 52 Issue 8, p4714-4720. 7p.
Subjects: Naphthalene, Lewis acids, Phosphine derivatives, Electronic structure, Boron, Crystallography
Abstract: Three naphtha-bridged phosphine-borane derivatives 2-BCy2, 2-BMes2, and 2-BFlu, differing in the steric and electronic properties of the boryl moiety, have been prepared and characterized by spectroscopic and crystallographic means. The presence and magnitude of the P → B interactions have been assessed experimentally and theoretically. The naphdiyl linker was found to enforce the P → B interaction despite steric shielding, while retaining enough flexibility to respond to the Lewis acidity of boron. [ABSTRACT FROM AUTHOR]
Copyright of Inorganic Chemistry is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P → B Interactions.
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  Data: <searchLink fieldCode="JN" term="%22Inorganic+Chemistry%22">Inorganic Chemistry</searchLink>. 4/15/2013, Vol. 52 Issue 8, p4714-4720. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Naphthalene%22">Naphthalene</searchLink><br /><searchLink fieldCode="DE" term="%22Lewis+acids%22">Lewis acids</searchLink><br /><searchLink fieldCode="DE" term="%22Phosphine+derivatives%22">Phosphine derivatives</searchLink><br /><searchLink fieldCode="DE" term="%22Electronic+structure%22">Electronic structure</searchLink><br /><searchLink fieldCode="DE" term="%22Boron%22">Boron</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallography%22">Crystallography</searchLink>
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  Data: Three naphtha-bridged phosphine-borane derivatives 2-BCy2, 2-BMes2, and 2-BFlu, differing in the steric and electronic properties of the boryl moiety, have been prepared and characterized by spectroscopic and crystallographic means. The presence and magnitude of the P → B interactions have been assessed experimentally and theoretically. The naphdiyl linker was found to enforce the P → B interaction despite steric shielding, while retaining enough flexibility to respond to the Lewis acidity of boron. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Inorganic Chemistry is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1021/ic4003466
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        Text: English
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      – SubjectFull: Lewis acids
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      – SubjectFull: Phosphine derivatives
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              Text: 4/15/2013
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