Fabrications and evaluations of hydrogen permeation on Al2O3/CeO2/graphene (ACG) composites membrane by Hot Press Sintering (HPS).

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Title: Fabrications and evaluations of hydrogen permeation on Al2O3/CeO2/graphene (ACG) composites membrane by Hot Press Sintering (HPS).
Authors: Lee, Na-Ri1, Lee, Soo-Sun1, Kim, Kyoeng-Il1, Kim, Whan-Gi2, Ju, Hyunchul3, Kim, Dong Min4, Hong, Tae-Whan1 twhong@ut.ac.kr
Source: International Journal of Hydrogen Energy. Jun2013, Vol. 38 Issue 18, p7654-7658. 5p.
Subjects: Composite materials, Aluminum oxide, Hydrogen, Graphene, Sintering, Microfabrication, Chemical stability, Temperature effect, Differential thermal analysis, X-ray diffraction
Abstract: Abstract: Ceramic membrane has high permeation rate of hydrogen and chemical stability. Al2O3 indicates stable at high temperature and a relatively large surface area. In addition, Al2O3 of porous is used as hydrogen separation membranes support, because of the high hydrogen permeability based on Knudsen diffusion mechanism. In this work, metal alkoxides as starting materials was used Aluminum isopropoxide powder. Then CeO2 as catalyst at the partial oxidation and Graphene Oxide as electrical conductivity are added, Al2O3–CeO2–Graphene oxide (ACG) composites are synthesized by sol–gel process. ACG membrane was fabricated type of disk by Hot Press Sintering. A synthesized ACG composite material was characterized by EDS, SEM, TG/DTA, XRD, BET. The hydrogen permeation property of ACG membrane was measured by Sievert's type hydrogen permeation membrane equipment. The hydrogen permeability of ACG membranes was examined at RT-673 K under increasing pressure. Results, hydrogen permeability was obtained to 2.62 × 10−7 mol/ms Pa1/2 at 673 K under 0.3 MPa. [Copyright &y& Elsevier]
Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Fabrications and evaluations of hydrogen permeation on Al<subscript>2</subscript>O<subscript>3</subscript>/CeO<subscript>2</subscript>/graphene (ACG) composites membrane by Hot Press Sintering (HPS).
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  Data: <searchLink fieldCode="AR" term="%22Lee%2C+Na-Ri%22">Lee, Na-Ri</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Lee%2C+Soo-Sun%22">Lee, Soo-Sun</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kim%2C+Kyoeng-Il%22">Kim, Kyoeng-Il</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kim%2C+Whan-Gi%22">Kim, Whan-Gi</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Ju%2C+Hyunchul%22">Ju, Hyunchul</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Kim%2C+Dong+Min%22">Kim, Dong Min</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Hong%2C+Tae-Whan%22">Hong, Tae-Whan</searchLink><relatesTo>1</relatesTo><i> twhong@ut.ac.kr</i>
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  Data: <searchLink fieldCode="JN" term="%22International+Journal+of+Hydrogen+Energy%22">International Journal of Hydrogen Energy</searchLink>. Jun2013, Vol. 38 Issue 18, p7654-7658. 5p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Aluminum+oxide%22">Aluminum oxide</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen%22">Hydrogen</searchLink><br /><searchLink fieldCode="DE" term="%22Graphene%22">Graphene</searchLink><br /><searchLink fieldCode="DE" term="%22Sintering%22">Sintering</searchLink><br /><searchLink fieldCode="DE" term="%22Microfabrication%22">Microfabrication</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+stability%22">Chemical stability</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature+effect%22">Temperature effect</searchLink><br /><searchLink fieldCode="DE" term="%22Differential+thermal+analysis%22">Differential thermal analysis</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Ceramic membrane has high permeation rate of hydrogen and chemical stability. Al2O3 indicates stable at high temperature and a relatively large surface area. In addition, Al2O3 of porous is used as hydrogen separation membranes support, because of the high hydrogen permeability based on Knudsen diffusion mechanism. In this work, metal alkoxides as starting materials was used Aluminum isopropoxide powder. Then CeO2 as catalyst at the partial oxidation and Graphene Oxide as electrical conductivity are added, Al2O3–CeO2–Graphene oxide (ACG) composites are synthesized by sol–gel process. ACG membrane was fabricated type of disk by Hot Press Sintering. A synthesized ACG composite material was characterized by EDS, SEM, TG/DTA, XRD, BET. The hydrogen permeation property of ACG membrane was measured by Sievert's type hydrogen permeation membrane equipment. The hydrogen permeability of ACG membranes was examined at RT-673 K under increasing pressure. Results, hydrogen permeability was obtained to 2.62 × 10−7 mol/ms Pa1/2 at 673 K under 0.3 MPa. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of International Journal of Hydrogen Energy is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.ijhydene.2012.08.080
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 5
        StartPage: 7654
    Subjects:
      – SubjectFull: Composite materials
        Type: general
      – SubjectFull: Aluminum oxide
        Type: general
      – SubjectFull: Hydrogen
        Type: general
      – SubjectFull: Graphene
        Type: general
      – SubjectFull: Sintering
        Type: general
      – SubjectFull: Microfabrication
        Type: general
      – SubjectFull: Chemical stability
        Type: general
      – SubjectFull: Temperature effect
        Type: general
      – SubjectFull: Differential thermal analysis
        Type: general
      – SubjectFull: X-ray diffraction
        Type: general
    Titles:
      – TitleFull: Fabrications and evaluations of hydrogen permeation on Al2O3/CeO2/graphene (ACG) composites membrane by Hot Press Sintering (HPS).
        Type: main
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            NameFull: Lee, Na-Ri
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            NameFull: Lee, Soo-Sun
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            NameFull: Kim, Kyoeng-Il
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            NameFull: Kim, Whan-Gi
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            NameFull: Ju, Hyunchul
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            NameFull: Kim, Dong Min
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            NameFull: Hong, Tae-Whan
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            – D: 18
              M: 06
              Text: Jun2013
              Type: published
              Y: 2013
          Identifiers:
            – Type: issn-print
              Value: 03603199
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            – TitleFull: International Journal of Hydrogen Energy
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