View in EDS

The reactivity of the dinuclear halo-bridged cycloplatinated complex [Pt(μ-Cl){(κ2-P,C)P(OC6H4)(OPh)2}]2 towards neutral ligands.

Saved in:
Bibliographic Details
Title: The reactivity of the dinuclear halo-bridged cycloplatinated complex [Pt(μ-Cl){(κ2-P,C)P(OC6H4)(OPh)2}]2 towards neutral ligands.
Authors: Dell'Amico, Daniela Belli1 belli@dcci.unipi.it, Labella, Luca1, Marchetti, Fabio1, Samaritani, Simona1
Source: Journal of Organometallic Chemistry. Jun2013, Vol. 733, p9-14. 6p.
Subjects: Platinum compounds, Metal complexes, Chemical reactions, Ligands (Chemistry), Ethylene, Isomers, Chemical equilibrium
Abstract: Abstract: The reactivity of (cis- + trans-)[Pt(μ-Cl){(κ2-P,C)P(OC6H4)(OPh)2}]2 (1) towards several ligands L (L = RCN, P(OMe)3, DMSO, NHEt2, py, CO, C2H4, C8H16) has been studied. Ethylene and 1-octene do not react while the other reactions proceed with cleavage of the halide bridge and formation of one or both geometrical isomers of [PtCl{(κ2-P,C)P(OC6H4)(OPh)2}L] (2–8) depending on the nature of the entering ligand. In some cases equilibrium reactions (L = RCN, DMSO, CO, py) were observed. The structures of [SP4-3]-[PtCl{(κ2-P,C)P(OC6H4)(OPh)2}(S)DMSO] ([SP4-3]-4) and [SP4-4]-[[PtCl{(κ2-P,C)P(OC6H4)(OPh)2}py] ([SP4-4]-6) are reported. [Copyright &y& Elsevier]
Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 89194138
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: The reactivity of the dinuclear halo-bridged cycloplatinated complex [Pt(μ-Cl){(κ<superscript>2</superscript>-P,C)P(OC<subscript>6</subscript>H<subscript>4</subscript>)(OPh)<subscript>2</subscript>}]<subscript>2</subscript> towards neutral ligands.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Dell'Amico%2C+Daniela+Belli%22">Dell'Amico, Daniela Belli</searchLink><relatesTo>1</relatesTo><i> belli@dcci.unipi.it</i><br /><searchLink fieldCode="AR" term="%22Labella%2C+Luca%22">Labella, Luca</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Marchetti%2C+Fabio%22">Marchetti, Fabio</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Samaritani%2C+Simona%22">Samaritani, Simona</searchLink><relatesTo>1</relatesTo>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Journal+of+Organometallic+Chemistry%22">Journal of Organometallic Chemistry</searchLink>. Jun2013, Vol. 733, p9-14. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Platinum+compounds%22">Platinum compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+complexes%22">Metal complexes</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Ethylene%22">Ethylene</searchLink><br /><searchLink fieldCode="DE" term="%22Isomers%22">Isomers</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+equilibrium%22">Chemical equilibrium</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: The reactivity of (cis- + trans-)[Pt(μ-Cl){(κ2-P,C)P(OC6H4)(OPh)2}]2 (1) towards several ligands L (L = RCN, P(OMe)3, DMSO, NHEt2, py, CO, C2H4, C8H16) has been studied. Ethylene and 1-octene do not react while the other reactions proceed with cleavage of the halide bridge and formation of one or both geometrical isomers of [PtCl{(κ2-P,C)P(OC6H4)(OPh)2}L] (2–8) depending on the nature of the entering ligand. In some cases equilibrium reactions (L = RCN, DMSO, CO, py) were observed. The structures of [SP4-3]-[PtCl{(κ2-P,C)P(OC6H4)(OPh)2}(S)DMSO] ([SP4-3]-4) and [SP4-4]-[[PtCl{(κ2-P,C)P(OC6H4)(OPh)2}py] ([SP4-4]-6) are reported. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=89194138
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jorganchem.2013.02.031
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 9
    Subjects:
      – SubjectFull: Platinum compounds
        Type: general
      – SubjectFull: Metal complexes
        Type: general
      – SubjectFull: Chemical reactions
        Type: general
      – SubjectFull: Ligands (Chemistry)
        Type: general
      – SubjectFull: Ethylene
        Type: general
      – SubjectFull: Isomers
        Type: general
      – SubjectFull: Chemical equilibrium
        Type: general
    Titles:
      – TitleFull: The reactivity of the dinuclear halo-bridged cycloplatinated complex [Pt(μ-Cl){(κ2-P,C)P(OC6H4)(OPh)2}]2 towards neutral ligands.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Dell'Amico, Daniela Belli
      – PersonEntity:
          Name:
            NameFull: Labella, Luca
      – PersonEntity:
          Name:
            NameFull: Marchetti, Fabio
      – PersonEntity:
          Name:
            NameFull: Samaritani, Simona
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 06
              Text: Jun2013
              Type: published
              Y: 2013
          Identifiers:
            – Type: issn-print
              Value: 0022328X
          Numbering:
            – Type: volume
              Value: 733
          Titles:
            – TitleFull: Journal of Organometallic Chemistry
              Type: main
ResultId 1