Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes.
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| Title: | Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes. |
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| Authors: | Gupta, Samik1, Kirillova, Marina V.1 kirillova@ist.utl.pt, Guedes da Silva, M. Fátima1,2 fatima.guedes@ist.utl.pt, Pombeiro, Armando J.L.1 pombeiro@ist.utl.pt |
| Source: | Applied Catalysis A: General. Jun2013, Vol. 460-461, p82-89. 8p. |
| Subjects: | Vanadium catalysts, Oxidation of alkanes, Liquids, Nitrogen dioxide, Schiff bases, Complex compounds synthesis |
| Abstract: | Highlights: [•] New binuclear V(V) complex bearing an NO2-donor Schiff base ligand is synthesized. [•] This compound is highly active catalyst precursor in the oxidation of alkanes by H2O2. [•] 2-Pyrazinecarboxylic acid acts as an efficient co-catalyst. [•] High yields (up to 45% based on alkanes) and TONs (up to 7800) are achieved. [•] Oxidation proceeds via radical mechanism with participation of hydroxyl radicals. [Copyright &y& Elsevier] |
| Copyright of Applied Catalysis A: General is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 89279344 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Gupta%2C+Samik%22">Gupta, Samik</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kirillova%2C+Marina+V%2E%22">Kirillova, Marina V.</searchLink><relatesTo>1</relatesTo><i> kirillova@ist.utl.pt</i><br /><searchLink fieldCode="AR" term="%22Guedes+da+Silva%2C+M%2E+Fátima%22">Guedes da Silva, M. Fátima</searchLink><relatesTo>1,2</relatesTo><i> fatima.guedes@ist.utl.pt</i><br /><searchLink fieldCode="AR" term="%22Pombeiro%2C+Armando+J%2EL%2E%22">Pombeiro, Armando J.L.</searchLink><relatesTo>1</relatesTo><i> pombeiro@ist.utl.pt</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Applied+Catalysis+A%3A+General%22">Applied Catalysis A: General</searchLink>. Jun2013, Vol. 460-461, p82-89. 8p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Vanadium+catalysts%22">Vanadium catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation+of+alkanes%22">Oxidation of alkanes</searchLink><br /><searchLink fieldCode="DE" term="%22Liquids%22">Liquids</searchLink><br /><searchLink fieldCode="DE" term="%22Nitrogen+dioxide%22">Nitrogen dioxide</searchLink><br /><searchLink fieldCode="DE" term="%22Schiff+bases%22">Schiff bases</searchLink><br /><searchLink fieldCode="DE" term="%22Complex+compounds+synthesis%22">Complex compounds synthesis</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Highlights: [•] New binuclear V(V) complex bearing an NO2-donor Schiff base ligand is synthesized. [•] This compound is highly active catalyst precursor in the oxidation of alkanes by H2O2. [•] 2-Pyrazinecarboxylic acid acts as an efficient co-catalyst. [•] High yields (up to 45% based on alkanes) and TONs (up to 7800) are achieved. [•] Oxidation proceeds via radical mechanism with participation of hydroxyl radicals. [Copyright &y& Elsevier] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Applied Catalysis A: General is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.apcata.2013.03.034 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 8 StartPage: 82 Subjects: – SubjectFull: Vanadium catalysts Type: general – SubjectFull: Oxidation of alkanes Type: general – SubjectFull: Liquids Type: general – SubjectFull: Nitrogen dioxide Type: general – SubjectFull: Schiff bases Type: general – SubjectFull: Complex compounds synthesis Type: general Titles: – TitleFull: Highly efficient divanadium(V) pre-catalyst for mild oxidation of liquid and gaseous alkanes. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Gupta, Samik – PersonEntity: Name: NameFull: Kirillova, Marina V. – PersonEntity: Name: NameFull: Guedes da Silva, M. Fátima – PersonEntity: Name: NameFull: Pombeiro, Armando J.L. IsPartOfRelationships: – BibEntity: Dates: – D: 10 M: 06 Text: Jun2013 Type: published Y: 2013 Identifiers: – Type: issn-print Value: 0926860X Numbering: – Type: volume Value: 460-461 Titles: – TitleFull: Applied Catalysis A: General Type: main |
| ResultId | 1 |
