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Adsorption of SOx by oxide materials: A review.

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Title: Adsorption of SOx by oxide materials: A review.
Authors: Mathieu, Yannick1, Tzanis, Lydie1, Soulard, Michel1, Patarin, Joël1 joel.patarin@uha.fr, Vierling, Matthieu2, Molière, Michel2
Source: Fuel Processing Technology. Oct2013, Vol. 114, p81-100. 20p.
Subjects: Adsorption (Chemistry), Sulfur oxides, Sorbents, Porous silica, Performance evaluation, Zeolites, Mesoporous materials
Abstract: Abstract: This paper is an attempt to provide a review — as extensive as feasible — of the literature devoted to the wide variety of sorbent systems that are currently either in use or under laboratory investigation for the removal of the SOx (SO2 +SO3) from flue gases. From an industrial perspective and besides any economic consideration, “the ideal” SOx sorbent candidate must ally four essential qualities some of which may appear contradictory to some extent: a strong affinity of the sorbent towards SOx along with fast kinetics; a large specific surface; a high physical/thermal/chemical stability and the capability for multiple regenerations at a reasonable temperature and with performance recoveries close to 100%. In this paper, the sorbent are classified in four categories which are: (i) single oxides; (ii) mixed oxides (including spinels and alumina supported oxides); (iii) oxides supported on carbonaceous materials and (iv) oxides supported on zeolites and mesoporous materials. A noteworthy outcome of this review lies in the promising prospects offered by porous silica-based materials as desulfurization (“DeSOx”) candidates and the interest of elaborating in this direction. [Copyright &y& Elsevier]
Copyright of Fuel Processing Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 89279511
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
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  Label: Title
  Group: Ti
  Data: Adsorption of SO<subscript>x</subscript> by oxide materials: A review.
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  Data: <searchLink fieldCode="AR" term="%22Mathieu%2C+Yannick%22">Mathieu, Yannick</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Tzanis%2C+Lydie%22">Tzanis, Lydie</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Soulard%2C+Michel%22">Soulard, Michel</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Patarin%2C+Joël%22">Patarin, Joël</searchLink><relatesTo>1</relatesTo><i> joel.patarin@uha.fr</i><br /><searchLink fieldCode="AR" term="%22Vierling%2C+Matthieu%22">Vierling, Matthieu</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Molière%2C+Michel%22">Molière, Michel</searchLink><relatesTo>2</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Fuel+Processing+Technology%22">Fuel Processing Technology</searchLink>. Oct2013, Vol. 114, p81-100. 20p.
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  Data: <searchLink fieldCode="DE" term="%22Adsorption+%28Chemistry%29%22">Adsorption (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Sulfur+oxides%22">Sulfur oxides</searchLink><br /><searchLink fieldCode="DE" term="%22Sorbents%22">Sorbents</searchLink><br /><searchLink fieldCode="DE" term="%22Porous+silica%22">Porous silica</searchLink><br /><searchLink fieldCode="DE" term="%22Performance+evaluation%22">Performance evaluation</searchLink><br /><searchLink fieldCode="DE" term="%22Zeolites%22">Zeolites</searchLink><br /><searchLink fieldCode="DE" term="%22Mesoporous+materials%22">Mesoporous materials</searchLink>
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  Data: Abstract: This paper is an attempt to provide a review — as extensive as feasible — of the literature devoted to the wide variety of sorbent systems that are currently either in use or under laboratory investigation for the removal of the SOx (SO2 +SO3) from flue gases. From an industrial perspective and besides any economic consideration, “the ideal” SOx sorbent candidate must ally four essential qualities some of which may appear contradictory to some extent: a strong affinity of the sorbent towards SOx along with fast kinetics; a large specific surface; a high physical/thermal/chemical stability and the capability for multiple regenerations at a reasonable temperature and with performance recoveries close to 100%. In this paper, the sorbent are classified in four categories which are: (i) single oxides; (ii) mixed oxides (including spinels and alumina supported oxides); (iii) oxides supported on carbonaceous materials and (iv) oxides supported on zeolites and mesoporous materials. A noteworthy outcome of this review lies in the promising prospects offered by porous silica-based materials as desulfurization (“DeSOx”) candidates and the interest of elaborating in this direction. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Fuel Processing Technology is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.fuproc.2013.03.019
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      – Code: eng
        Text: English
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        PageCount: 20
        StartPage: 81
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      – SubjectFull: Adsorption (Chemistry)
        Type: general
      – SubjectFull: Sulfur oxides
        Type: general
      – SubjectFull: Sorbents
        Type: general
      – SubjectFull: Porous silica
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      – SubjectFull: Performance evaluation
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      – SubjectFull: Zeolites
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      – SubjectFull: Mesoporous materials
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    Titles:
      – TitleFull: Adsorption of SOx by oxide materials: A review.
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            NameFull: Tzanis, Lydie
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            NameFull: Soulard, Michel
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              M: 10
              Text: Oct2013
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