Why is the CO2–CS2 non-ideality larger than in CO2–CCl4? A Raman scattering study.

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Title: Why is the CO2–CS2 non-ideality larger than in CO2–CCl4? A Raman scattering study.
Authors: Besnard, M.1 m.besnard@ism.u-bordeaux1.fr, Cabaço, M.I.2, Coutinho, J.A.P.3, Danten, Y.1
Source: Chemical Physics Letters. Sep2013, Vol. 583, p49-53. 5p.
Subjects: Carbon dioxide, Carbon disulfide, Raman scattering, Mixtures, Liquid-liquid interfaces, Low temperatures
Abstract: Highlights: [•] Raman spectroscopic study of CO2–CCl4 and CO2–CS2 mixtures at 313K. [•] CO2–CCl4 is found almost ideal and CO2–CS2 strongly non-ideal. [•] Nano-segregation without demixing in CS2 concentrated mixtures. [•] A diversity of species are present in CO2 concentrated mixtures. [•] The connection with the liquid–liquid demixing at lower temperature is discussed. [ABSTRACT FROM AUTHOR]
Copyright of Chemical Physics Letters is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Why is the CO<subscript>2</subscript>–CS<subscript>2</subscript> non-ideality larger than in CO<subscript>2</subscript>–CCl<subscript>4</subscript>? A Raman scattering study.
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  Data: <searchLink fieldCode="AR" term="%22Besnard%2C+M%2E%22">Besnard, M.</searchLink><relatesTo>1</relatesTo><i> m.besnard@ism.u-bordeaux1.fr</i><br /><searchLink fieldCode="AR" term="%22Cabaço%2C+M%2EI%2E%22">Cabaço, M.I.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Coutinho%2C+J%2EA%2EP%2E%22">Coutinho, J.A.P.</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Danten%2C+Y%2E%22">Danten, Y.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Chemical+Physics+Letters%22">Chemical Physics Letters</searchLink>. Sep2013, Vol. 583, p49-53. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Carbon+dioxide%22">Carbon dioxide</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon+disulfide%22">Carbon disulfide</searchLink><br /><searchLink fieldCode="DE" term="%22Raman+scattering%22">Raman scattering</searchLink><br /><searchLink fieldCode="DE" term="%22Mixtures%22">Mixtures</searchLink><br /><searchLink fieldCode="DE" term="%22Liquid-liquid+interfaces%22">Liquid-liquid interfaces</searchLink><br /><searchLink fieldCode="DE" term="%22Low+temperatures%22">Low temperatures</searchLink>
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  Label: Abstract
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  Data: Highlights: [•] Raman spectroscopic study of CO2–CCl4 and CO2–CS2 mixtures at 313K. [•] CO2–CCl4 is found almost ideal and CO2–CS2 strongly non-ideal. [•] Nano-segregation without demixing in CS2 concentrated mixtures. [•] A diversity of species are present in CO2 concentrated mixtures. [•] The connection with the liquid–liquid demixing at lower temperature is discussed. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Chemical Physics Letters is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.cplett.2013.07.061
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      – Code: eng
        Text: English
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        Type: general
      – SubjectFull: Carbon disulfide
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      – SubjectFull: Raman scattering
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      – SubjectFull: Mixtures
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      – SubjectFull: Liquid-liquid interfaces
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      – SubjectFull: Low temperatures
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      – TitleFull: Why is the CO2–CS2 non-ideality larger than in CO2–CCl4? A Raman scattering study.
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              Text: Sep2013
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