Correlation between structural, magnetic and electrical transport properties of barium vacancies in the La0.67Ba0.33− x □ x MnO3 (x =0, 0.05, and 0.1) manganite.

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Title: Correlation between structural, magnetic and electrical transport properties of barium vacancies in the La0.67Ba0.33− x x MnO3 (x =0, 0.05, and 0.1) manganite.
Authors: Oumezzine, Marwène1,2 Oumezzine@hotmail.co.uk, Kallel, Sami1, Peña, Octavio2, Kallel, Nabil1, Guizouarn, Thierry2, Gouttefangeas, Francis3, Oumezzine, Mohamed1
Source: Journal of Alloys & Compounds. Jan2014, Vol. 582, p640-646. 7p.
Subjects: Barium compounds, Manganese oxides, Manganite, Magnetic properties of metals, Electric properties of metals, Metals at low temperatures, Percolation theory, Curie temperature
Abstract: Highlights: [•] La0.67Ba0.33x□ x MnO3 manganites crystallize in the rhombohedral structure. [•] Barium vacancies modify the structural parameters such as the volume, the Mn–O bond length and the Mn–O–Mn angles. [•] La0.67Ba0.33x□ x MnO3 exhibit a PM-semiconducting state at high temperatures and a FM-metallic state at low temperatures. [•] The resistivity is described in terms of percolation phase theory in the whole range of temperatures. [•] The Curie temperature TC and the electrical transition temperature T M-SC decrease with increasing barium deficiencies. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
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