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Electrochemically induced C H functionalization using bromide ion/2,2,6,6-tetramethylpiperidinyl-N-oxyl dual redox catalysts in a two-phase electrolytic system.

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Title: Electrochemically induced C H functionalization using bromide ion/2,2,6,6-tetramethylpiperidinyl-N-oxyl dual redox catalysts in a two-phase electrolytic system.
Authors: Li, Chao1,2, Zeng, Cheng-Chu1 zengcc@bjut.edu.cn, Hu, Li-Ming1, Yang, Feng-Lin2,3, Yoo, Seung Joon4, Little, R. Daniel4 little@chem.ucsb.edu
Source: Electrochimica Acta. Dec2013, Vol. 114, p560-566. 7p.
Subjects: Electrochemistry, Bromide ions, Oxidation-reduction reaction, Catalysis, Electrochemical analysis, Chemical bonds, Substrates (Materials science)
Abstract: Highlights: [•] Electrocatalytic C H bond functionalization of tetrahydroisoquinolines is reported. [•] The transformation is mediated by a bromide ion/TEMPO dual redox catalyst system. [•] The transformation is conducted in a two-phase electrolytic medium. [•] The mechanism is proposed to proceed via a sequence of oxidation and addition reactions involving water as a nucleophile. [•] The procedure features wide substrate scope, the use of mild reaction conditions. [Copyright &y& Elsevier]
Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 92905770
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Electrochemically induced C H functionalization using bromide ion/2,2,6,6-tetramethylpiperidinyl-N-oxyl dual redox catalysts in a two-phase electrolytic system.
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  Data: <searchLink fieldCode="AR" term="%22Li%2C+Chao%22">Li, Chao</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Zeng%2C+Cheng-Chu%22">Zeng, Cheng-Chu</searchLink><relatesTo>1</relatesTo><i> zengcc@bjut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Hu%2C+Li-Ming%22">Hu, Li-Ming</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yang%2C+Feng-Lin%22">Yang, Feng-Lin</searchLink><relatesTo>2,3</relatesTo><br /><searchLink fieldCode="AR" term="%22Yoo%2C+Seung+Joon%22">Yoo, Seung Joon</searchLink><relatesTo>4</relatesTo><br /><searchLink fieldCode="AR" term="%22Little%2C+R%2E+Daniel%22">Little, R. Daniel</searchLink><relatesTo>4</relatesTo><i> little@chem.ucsb.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Electrochimica+Acta%22">Electrochimica Acta</searchLink>. Dec2013, Vol. 114, p560-566. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Electrochemistry%22">Electrochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Bromide+ions%22">Bromide ions</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation-reduction+reaction%22">Oxidation-reduction reaction</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+analysis%22">Electrochemical analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+bonds%22">Chemical bonds</searchLink><br /><searchLink fieldCode="DE" term="%22Substrates+%28Materials+science%29%22">Substrates (Materials science)</searchLink>
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  Data: Highlights: [•] Electrocatalytic C H bond functionalization of tetrahydroisoquinolines is reported. [•] The transformation is mediated by a bromide ion/TEMPO dual redox catalyst system. [•] The transformation is conducted in a two-phase electrolytic medium. [•] The mechanism is proposed to proceed via a sequence of oxidation and addition reactions involving water as a nucleophile. [•] The procedure features wide substrate scope, the use of mild reaction conditions. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.electacta.2013.10.093
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        Text: English
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      – SubjectFull: Electrochemistry
        Type: general
      – SubjectFull: Bromide ions
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      – SubjectFull: Oxidation-reduction reaction
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      – SubjectFull: Catalysis
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      – TitleFull: Electrochemically induced C H functionalization using bromide ion/2,2,6,6-tetramethylpiperidinyl-N-oxyl dual redox catalysts in a two-phase electrolytic system.
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              Text: Dec2013
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              Y: 2013
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