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Gellified ionic liquid based composite electrolytes—Influence of different silica as filler materials on electrical and mechanical properties of the electrolyte.

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Title: Gellified ionic liquid based composite electrolytes—Influence of different silica as filler materials on electrical and mechanical properties of the electrolyte.
Authors: Krawczyk, N.1, Vogel, J.2, Luerßen, B.1, Fröba, M.2 froeba@chemie.uni-hamburg.de, Janek, J.1,3 Juergen.Janek@phys.chemie.uni-giessen.de
Source: Electrochemistry Communications. Feb2014, Vol. 39, p34-36. 3p.
Subjects: Ionic liquids, Composite materials, Electrolytes, Imides, Silica, Filler materials, Electric properties of materials, Mechanical behavior of materials
Abstract: Abstract: The electrical and mechanical properties of N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfon)imide (BMP-TFSI) lithium electrolyte with 15wt.% LiTFSI as conducting salt are reported. The conductivity and the viscosity for the neat electrolyte as well as for IL/solid dispersions with different types of silica nanoparticles (commercially available silica nanoparticles, mesoporous KIT-6 silica and surface-modified silica nanoparticles) as second phase are reported. Systematic conductivity and viscosity data are presented, and their correlation suggests that the partial conductivity of at least one ion is enhanced. It is concluded that an interface effect is indeed responsible for this effect. [Copyright &y& Elsevier]
Copyright of Electrochemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 93591744
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Gellified ionic liquid based composite electrolytes—Influence of different silica as filler materials on electrical and mechanical properties of the electrolyte.
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  Data: <searchLink fieldCode="AR" term="%22Krawczyk%2C+N%2E%22">Krawczyk, N.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Vogel%2C+J%2E%22">Vogel, J.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Luerßen%2C+B%2E%22">Luerßen, B.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Fröba%2C+M%2E%22">Fröba, M.</searchLink><relatesTo>2</relatesTo><i> froeba@chemie.uni-hamburg.de</i><br /><searchLink fieldCode="AR" term="%22Janek%2C+J%2E%22">Janek, J.</searchLink><relatesTo>1,3</relatesTo><i> Juergen.Janek@phys.chemie.uni-giessen.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Electrochemistry+Communications%22">Electrochemistry Communications</searchLink>. Feb2014, Vol. 39, p34-36. 3p.
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  Data: <searchLink fieldCode="DE" term="%22Ionic+liquids%22">Ionic liquids</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolytes%22">Electrolytes</searchLink><br /><searchLink fieldCode="DE" term="%22Imides%22">Imides</searchLink><br /><searchLink fieldCode="DE" term="%22Silica%22">Silica</searchLink><br /><searchLink fieldCode="DE" term="%22Filler+materials%22">Filler materials</searchLink><br /><searchLink fieldCode="DE" term="%22Electric+properties+of+materials%22">Electric properties of materials</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink>
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  Data: Abstract: The electrical and mechanical properties of N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfon)imide (BMP-TFSI) lithium electrolyte with 15wt.% LiTFSI as conducting salt are reported. The conductivity and the viscosity for the neat electrolyte as well as for IL/solid dispersions with different types of silica nanoparticles (commercially available silica nanoparticles, mesoporous KIT-6 silica and surface-modified silica nanoparticles) as second phase are reported. Systematic conductivity and viscosity data are presented, and their correlation suggests that the partial conductivity of at least one ion is enhanced. It is concluded that an interface effect is indeed responsible for this effect. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Electrochemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.elecom.2013.11.025
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      – Code: eng
        Text: English
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        PageCount: 3
        StartPage: 34
    Subjects:
      – SubjectFull: Ionic liquids
        Type: general
      – SubjectFull: Composite materials
        Type: general
      – SubjectFull: Electrolytes
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      – SubjectFull: Imides
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      – SubjectFull: Silica
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      – SubjectFull: Filler materials
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      – SubjectFull: Electric properties of materials
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      – SubjectFull: Mechanical behavior of materials
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      – TitleFull: Gellified ionic liquid based composite electrolytes—Influence of different silica as filler materials on electrical and mechanical properties of the electrolyte.
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              Text: Feb2014
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              Y: 2014
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