View in EDS

A norbornene polymer brush for electro-optic applications.

Saved in:
Bibliographic Details
Title: A norbornene polymer brush for electro-optic applications.
Authors: Jia, Yue1, Spring, Andrew M.1, Yu, Feng1, Yamamoto, Kazuhiro1, Aoki, Isao2, Otomo, Akira2, Yokoyama, Shiyoshi1 s_yokoyama@cm.kyushu-u.ac.jp
Source: Thin Solid Films. Mar2014, Vol. 554, p175-179. 5p.
Subjects: Polymers, Electrooptics, Dicarboximides, Dispersion (Chemistry), Chromophores, Chemical preparations industry, Ring formation (Chemistry)
Abstract: Abstract: Norbornene-dicarboximide derived polymer brushes containing Disperse Red 1 appended chromophores have been prepared by sequencial ring opening metathesis polymerization and atom transfer radical polymerization. This brush was then employed as an electro-optic polymer host for high molecular hyperpolarizability phenyl vinylene thiophene vinylene (FTC) bridge chromophores in a binary chromophore system. The r33 of the polymer brush/bi-chromophore network was evaluated via in situ poling and was measured as 94pm/V compared to the benchmark polymethylmethacrylate (PMMA) system of 76pm/V with an identical chromophore. Furthermore, our polymer brush/bi-chromophore network exhibited an enhanced poling efficiency of 1.37 (nm/V)2 as compared to a simple PMMA - FTC host - guest 0.70 (nm/V)2. [Copyright &y& Elsevier]
Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 94407432
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: A norbornene polymer brush for electro-optic applications.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Jia%2C+Yue%22">Jia, Yue</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Spring%2C+Andrew+M%2E%22">Spring, Andrew M.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yu%2C+Feng%22">Yu, Feng</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yamamoto%2C+Kazuhiro%22">Yamamoto, Kazuhiro</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Aoki%2C+Isao%22">Aoki, Isao</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Otomo%2C+Akira%22">Otomo, Akira</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Yokoyama%2C+Shiyoshi%22">Yokoyama, Shiyoshi</searchLink><relatesTo>1</relatesTo><i> s_yokoyama@cm.kyushu-u.ac.jp</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Thin+Solid+Films%22">Thin Solid Films</searchLink>. Mar2014, Vol. 554, p175-179. 5p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Electrooptics%22">Electrooptics</searchLink><br /><searchLink fieldCode="DE" term="%22Dicarboximides%22">Dicarboximides</searchLink><br /><searchLink fieldCode="DE" term="%22Dispersion+%28Chemistry%29%22">Dispersion (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Chromophores%22">Chromophores</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+preparations+industry%22">Chemical preparations industry</searchLink><br /><searchLink fieldCode="DE" term="%22Ring+formation+%28Chemistry%29%22">Ring formation (Chemistry)</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Norbornene-dicarboximide derived polymer brushes containing Disperse Red 1 appended chromophores have been prepared by sequencial ring opening metathesis polymerization and atom transfer radical polymerization. This brush was then employed as an electro-optic polymer host for high molecular hyperpolarizability phenyl vinylene thiophene vinylene (FTC) bridge chromophores in a binary chromophore system. The r33 of the polymer brush/bi-chromophore network was evaluated via in situ poling and was measured as 94pm/V compared to the benchmark polymethylmethacrylate (PMMA) system of 76pm/V with an identical chromophore. Furthermore, our polymer brush/bi-chromophore network exhibited an enhanced poling efficiency of 1.37 (nm/V)2 as compared to a simple PMMA - FTC host - guest 0.70 (nm/V)2. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Thin Solid Films is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=94407432
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.tsf.2013.06.071
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 5
        StartPage: 175
    Subjects:
      – SubjectFull: Polymers
        Type: general
      – SubjectFull: Electrooptics
        Type: general
      – SubjectFull: Dicarboximides
        Type: general
      – SubjectFull: Dispersion (Chemistry)
        Type: general
      – SubjectFull: Chromophores
        Type: general
      – SubjectFull: Chemical preparations industry
        Type: general
      – SubjectFull: Ring formation (Chemistry)
        Type: general
    Titles:
      – TitleFull: A norbornene polymer brush for electro-optic applications.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Jia, Yue
      – PersonEntity:
          Name:
            NameFull: Spring, Andrew M.
      – PersonEntity:
          Name:
            NameFull: Yu, Feng
      – PersonEntity:
          Name:
            NameFull: Yamamoto, Kazuhiro
      – PersonEntity:
          Name:
            NameFull: Aoki, Isao
      – PersonEntity:
          Name:
            NameFull: Otomo, Akira
      – PersonEntity:
          Name:
            NameFull: Yokoyama, Shiyoshi
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 03
              M: 03
              Text: Mar2014
              Type: published
              Y: 2014
          Identifiers:
            – Type: issn-print
              Value: 00406090
          Numbering:
            – Type: volume
              Value: 554
          Titles:
            – TitleFull: Thin Solid Films
              Type: main
ResultId 1