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Electrochemical evaluation of carbon nanotubes and carbon black for the cathode of Li–air batteries.

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Title: Electrochemical evaluation of carbon nanotubes and carbon black for the cathode of Li–air batteries.
Authors: Fuentes, Roderick E.1, Colón-Mercado, Héctor R.1, Fox, Elise B.1 ebfox@bellsouth.net
Source: Journal of Power Sources. Jun2014, Vol. 255, p219-222. 4p.
Subjects: Lithium-ion batteries, Electrochemical analysis, Multiwalled carbon nanotubes, Carbon-black, Storage battery electrodes, Manganese oxides
Abstract: Abstract: Cyclic Voltammetry (CV) was used to screen carbon catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) performance as electrodes for the Li–air battery. Lithium bis(trifluoromethylsulfonyl)imide (LiTF2N) in tetraethylene glycol dimethyl ether (TEGDME) was used as the electrolyte during testing. The effect of manganese/manganese oxide addition on the performance of the carbons was compared to that of the bare carbons in a cycling study. From CV results, it was found that single walled carbon nanotubes (SWCNT) had the highest peak current density per gram for ORR and OER than the other types of carbon studied. The SWCNT ORR peak decreased 49% after 100 cycles and only 36% when manganese/manganese oxide was added. The high activity of SWCNT with manganese/manganese oxide spheres make it a desirable material to use as the cathode for Li–air batteries. [Copyright &y& Elsevier]
Copyright of Journal of Power Sources is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
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Header DbId: egs
DbLabel: Engineering Source
An: 94408345
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Electrochemical evaluation of carbon nanotubes and carbon black for the cathode of Li–air batteries.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Fuentes%2C+Roderick+E%2E%22">Fuentes, Roderick E.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Colón-Mercado%2C+Héctor+R%2E%22">Colón-Mercado, Héctor R.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Fox%2C+Elise+B%2E%22">Fox, Elise B.</searchLink><relatesTo>1</relatesTo><i> ebfox@bellsouth.net</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Journal+of+Power+Sources%22">Journal of Power Sources</searchLink>. Jun2014, Vol. 255, p219-222. 4p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Lithium-ion+batteries%22">Lithium-ion batteries</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+analysis%22">Electrochemical analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Multiwalled+carbon+nanotubes%22">Multiwalled carbon nanotubes</searchLink><br /><searchLink fieldCode="DE" term="%22Carbon-black%22">Carbon-black</searchLink><br /><searchLink fieldCode="DE" term="%22Storage+battery+electrodes%22">Storage battery electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Manganese+oxides%22">Manganese oxides</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Abstract: Cyclic Voltammetry (CV) was used to screen carbon catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) performance as electrodes for the Li–air battery. Lithium bis(trifluoromethylsulfonyl)imide (LiTF2N) in tetraethylene glycol dimethyl ether (TEGDME) was used as the electrolyte during testing. The effect of manganese/manganese oxide addition on the performance of the carbons was compared to that of the bare carbons in a cycling study. From CV results, it was found that single walled carbon nanotubes (SWCNT) had the highest peak current density per gram for ORR and OER than the other types of carbon studied. The SWCNT ORR peak decreased 49% after 100 cycles and only 36% when manganese/manganese oxide was added. The high activity of SWCNT with manganese/manganese oxide spheres make it a desirable material to use as the cathode for Li–air batteries. [Copyright &y& Elsevier]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Power Sources is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1016/j.jpowsour.2013.12.133
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 4
        StartPage: 219
    Subjects:
      – SubjectFull: Lithium-ion batteries
        Type: general
      – SubjectFull: Electrochemical analysis
        Type: general
      – SubjectFull: Multiwalled carbon nanotubes
        Type: general
      – SubjectFull: Carbon-black
        Type: general
      – SubjectFull: Storage battery electrodes
        Type: general
      – SubjectFull: Manganese oxides
        Type: general
    Titles:
      – TitleFull: Electrochemical evaluation of carbon nanotubes and carbon black for the cathode of Li–air batteries.
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            NameFull: Fuentes, Roderick E.
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            NameFull: Colón-Mercado, Héctor R.
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            NameFull: Fox, Elise B.
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          Dates:
            – D: 01
              M: 06
              Text: Jun2014
              Type: published
              Y: 2014
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              Value: 255
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            – TitleFull: Journal of Power Sources
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