Physicaland Thermophysical Properties of 1-Hexyl-1,4-diaza[2.2.2]bicyclooctaniumBis(trifluoromethylsulfonyl)imide Ionic Liquid.

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Title: Physicaland Thermophysical Properties of 1-Hexyl-1,4-diaza[2.2.2]bicyclooctaniumBis(trifluoromethylsulfonyl)imide Ionic Liquid.
Authors: Marcinkowski, Łukasz1, Kloskowski, Adam1, Namieśnik, Jacek1
Source: Journal of Chemical & Engineering Data. Mar2014, Vol. 59 Issue 3, p585-591. 7p.
Subjects: Thermophysical properties, Diazabicyclooctane, Sulfonyl compounds, Imides, Ionic liquids, Organic synthesis
Abstract: Owing to their unique properties,ionic liquids (ILs) have becomea real alternative to organic compounds. Nowadays, ILs are commonlyused in a number of areas such as chemical synthesis and separationtechniques. However, ionic liquids continue to have a limited applicabilityin industry because the information on their physical and chemicalproperties is not readily available. This paper presents, for thefirst time, the results of studies on 1-hexyl-1,4-diaza[2.2.2]bicyclooctaniumbis(trifluoromethylsulfonyl)imide ([HDABCO][NTf2]) ionicliquid which is relatively novel and not well researched. A wide rangeof properties, important from a point of view of potential applicationsof [HDABCO][NTf2], was examined. Parameters such as density,phase transition temperatures, long-term thermal stability, polarizability,hygroscopicity, and McReynolds constants have been determined. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
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Abstract:Owing to their unique properties,ionic liquids (ILs) have becomea real alternative to organic compounds. Nowadays, ILs are commonlyused in a number of areas such as chemical synthesis and separationtechniques. However, ionic liquids continue to have a limited applicabilityin industry because the information on their physical and chemicalproperties is not readily available. This paper presents, for thefirst time, the results of studies on 1-hexyl-1,4-diaza[2.2.2]bicyclooctaniumbis(trifluoromethylsulfonyl)imide ([HDABCO][NTf2]) ionicliquid which is relatively novel and not well researched. A wide rangeof properties, important from a point of view of potential applicationsof [HDABCO][NTf2], was examined. Parameters such as density,phase transition temperatures, long-term thermal stability, polarizability,hygroscopicity, and McReynolds constants have been determined. [ABSTRACT FROM AUTHOR]
ISSN:00219568
DOI:10.1021/je400252p