Electronic and geometrical structure of bicyclo[8.1.0]undec-1(10)-en-5-yn-11-one and related...
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| Title: | Electronic and geometrical structure of bicyclo[8.1.0]undec-1(10)-en-5-yn-11-one and related... |
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| Authors: | Gleiter, R., Merger, M. |
| Source: | Journal of Organic Chemistry. 7/28/95, Vol. 60 Issue 15, p4692. 5p. 16 Diagrams, 3 Charts, 5 Graphs. |
| Subjects: | Carbonyl compounds, Photoelectron spectroscopy, X-ray crystallography, Conformational analysis, Spectrum analysis |
| Abstract: | Investigates the helium(I) photoelectron spectra of bicyclo[8.1.0]undec-1(10)-en-5-yn-11-one and related compounds. Interpretation of spectra; Evidence for the interaction between the triple bond and the cyclopropenone moiety; Substantiation of results by X-ray investigations on crystals; Identification of a boat conformation for the 10-membered ring in the solid state. |
| Database: | Engineering Source |
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