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Polymorphism of 2-Adamantanone.

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Title: Polymorphism of 2-Adamantanone.
Authors: Negrier, P.1, Barrio, M.1, Romanini, M.1, Tamarit, J. Ll.1, Mondieig, D.1, Krivchikov, A. I.1, Kepinski, L.1, Jezowski, A.1, Szewczyk, D.1
Source: Crystal Growth & Design. May2014, Vol. 14 Issue 5, p2626-2632. 7p.
Subjects: Polymorphism (Crystallography), X-ray diffraction, High pressure chemistry, Thermal analysis, Crystal lattices, Phase diagrams
Abstract: Thepolymorphism of 2-adamantanone (C10H14O) hasbeen investigated by means of X-ray diffraction and high-pressurethermal analysis. The intricate behavior of the low-temperature crystallinephases has been disentangled. The stable phase has been found to beorthorhombic (Cmc21, Z= 4), fully ordered, with lattice parameters a=6.8884(18) Å, b= 10.830(3) Å, c= 10.658(3) Å, and V/Z= 198.8(1) Å3. The metastable phase was determinedto be monoclinic (P21/c, Z= 4) with lattice parameters a= 6.5920(17) Å, b= 11.118(3) Å, c= 12.589(3) Å, β= 118.869(11) o,and V/Z= 202.0(1) Å3. The pressure–temperature phase diagram irrefutably showsthe stability relation between both phases and, accordingly, the long-timeunknown polymorphic behavior is now revealed and gives coherent physicalexplanation of the literature published so far. [ABSTRACT FROM AUTHOR]
Copyright of Crystal Growth & Design is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 95960967
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  Data: Polymorphism of 2-Adamantanone.
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  Data: <searchLink fieldCode="JN" term="%22Crystal+Growth+%26+Design%22">Crystal Growth & Design</searchLink>. May2014, Vol. 14 Issue 5, p2626-2632. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Polymorphism+%28Crystallography%29%22">Polymorphism (Crystallography)</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22High+pressure+chemistry%22">High pressure chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+analysis%22">Thermal analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+lattices%22">Crystal lattices</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+diagrams%22">Phase diagrams</searchLink>
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  Data: Thepolymorphism of 2-adamantanone (C10H14O) hasbeen investigated by means of X-ray diffraction and high-pressurethermal analysis. The intricate behavior of the low-temperature crystallinephases has been disentangled. The stable phase has been found to beorthorhombic (Cmc21, Z= 4), fully ordered, with lattice parameters a=6.8884(18) Å, b= 10.830(3) Å, c= 10.658(3) Å, and V/Z= 198.8(1) Å3. The metastable phase was determinedto be monoclinic (P21/c, Z= 4) with lattice parameters a= 6.5920(17) Å, b= 11.118(3) Å, c= 12.589(3) Å, β= 118.869(11) o,and V/Z= 202.0(1) Å3. The pressure–temperature phase diagram irrefutably showsthe stability relation between both phases and, accordingly, the long-timeunknown polymorphic behavior is now revealed and gives coherent physicalexplanation of the literature published so far. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Crystal Growth & Design is the property of American Chemical Society and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1021/cg500313m
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      – SubjectFull: X-ray diffraction
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      – SubjectFull: High pressure chemistry
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      – SubjectFull: Thermal analysis
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      – SubjectFull: Crystal lattices
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      – SubjectFull: Phase diagrams
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      – TitleFull: Polymorphism of 2-Adamantanone.
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              M: 05
              Text: May2014
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