Methods to Quantify Reactive Chromium Vaporization from Solid Oxide Fuel Cell Interconnects.

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Title: Methods to Quantify Reactive Chromium Vaporization from Solid Oxide Fuel Cell Interconnects.
Authors: Key, C.1 ckey@phys.utb.edu, Eziashi, J.2, Froitzheim, J.3, Amendola, R.4, Smith, R.1, Gannon, P.2
Source: Journal of The Electrochemical Society. 2014, Vol. 161 Issue 9, pC373-C381. 9p.
Subjects: High temperature superconductivity, Chromium, Electric properties of stainless steel, Transpiration (Physics), Electrochemistry
Abstract: High-temperature (>600°C) reactive vaporization of Cr from chromia and stainless steels in oxidizing environments is an industrially relevant phenomenon that has been and will continue to be studied extensively for decades. Recently, many experimental techniques have been developed to measure Cr vaporization from stainless steel interconnect (IC) components within solid oxide fuel cell (SOFC) systems. Many of these techniques are based on an experimental method known as the transpiration method, which is used to generate Cr vapors and subsequently collect them for quantitative analysis. However, vapor collection and analysis methods differ significantly between investigators within the community, as does the array of alloys (with and without protective surface coatings), temperatures, flow rates, and water vapor pressures used in experimentation. Therefore, the purpose of the present work is to provide an overview of experimental techniques used to quantify reactive Cr vaporization, and to compare data reported in literature on Cr vaporization from Cr2O3 and chromium containing alloys in oxidizing environments. [ABSTRACT FROM AUTHOR]
Copyright of Journal of The Electrochemical Society is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Methods to Quantify Reactive Chromium Vaporization from Solid Oxide Fuel Cell Interconnects.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+The+Electrochemical+Society%22">Journal of The Electrochemical Society</searchLink>. 2014, Vol. 161 Issue 9, pC373-C381. 9p.
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  Data: <searchLink fieldCode="DE" term="%22High+temperature+superconductivity%22">High temperature superconductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Chromium%22">Chromium</searchLink><br /><searchLink fieldCode="DE" term="%22Electric+properties+of+stainless+steel%22">Electric properties of stainless steel</searchLink><br /><searchLink fieldCode="DE" term="%22Transpiration+%28Physics%29%22">Transpiration (Physics)</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemistry%22">Electrochemistry</searchLink>
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  Data: High-temperature (>600°C) reactive vaporization of Cr from chromia and stainless steels in oxidizing environments is an industrially relevant phenomenon that has been and will continue to be studied extensively for decades. Recently, many experimental techniques have been developed to measure Cr vaporization from stainless steel interconnect (IC) components within solid oxide fuel cell (SOFC) systems. Many of these techniques are based on an experimental method known as the transpiration method, which is used to generate Cr vapors and subsequently collect them for quantitative analysis. However, vapor collection and analysis methods differ significantly between investigators within the community, as does the array of alloys (with and without protective surface coatings), temperatures, flow rates, and water vapor pressures used in experimentation. Therefore, the purpose of the present work is to provide an overview of experimental techniques used to quantify reactive Cr vaporization, and to compare data reported in literature on Cr vaporization from Cr2O3 and chromium containing alloys in oxidizing environments. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Journal of The Electrochemical Society is the property of IOP Publishing and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1149/2.0041409jes
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: C373
    Subjects:
      – SubjectFull: High temperature superconductivity
        Type: general
      – SubjectFull: Chromium
        Type: general
      – SubjectFull: Electric properties of stainless steel
        Type: general
      – SubjectFull: Transpiration (Physics)
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      – SubjectFull: Electrochemistry
        Type: general
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      – TitleFull: Methods to Quantify Reactive Chromium Vaporization from Solid Oxide Fuel Cell Interconnects.
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              Text: 2014
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