Optimizing heavy-duty anticorrosive performances of coating films formed by acrylate-vinylidene chloride copolymer latexes through twice-painting technique.

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Title: Optimizing heavy-duty anticorrosive performances of coating films formed by acrylate-vinylidene chloride copolymer latexes through twice-painting technique.
Authors: Fu, Ce1, Zhang, Tong-xian1, Ji, Cheng-qi2, Cheng, Fa1, Cui, Wen-zhu3, Chen, Yu1 chenyu@tju.edu.cn
Source: Chinese Journal of Polymer Science (Springer Science & Business Media B.V.). Jan2015, Vol. 33 Issue 1, p14-22. 9p.
Subjects: Copolymers, Corrosion inhibitors, Surface coatings, Thin films, Acrylates, Dichloroethylene, Painting techniques
Abstract: Twice-painting technique was adopted to prepare heavy-duty anticorrosive coating films formed by aqueous latexes of copolymers of vinylidene chloride (VDC) with an acrylate, namely methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA) or 2-ethylhexyl acrylate (EHA). Harsh salt-spray corrosion tests demonstrated that the optimized twice-painting technique was that the acidic latex solution was adjusted to pH 5-6 for the first painting, while it was utilized directly for the second painting. The test of 600 h of harsh salt-spray corrosion showed that MA-VDC85 coating could protect the steel excellently, whereas the other acrylate-VDC coatings with 75%-90% VDC content could not protect the steel so effectively. Further corrosion test showed that (1) MA-VDC85 coating protected steel from loss of metallic luster for at least 1000 h of salt-spray corrosion; (2) adhesion of MA-VDC85 coating to steel was excellent for at least 800 h of salt-spray corrosion, but became very poor after 1000 h. Differential scanning calorimetry, thermogravimetric analysis, X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy were used to evaluate the corroded MA-VDC85 film. [ABSTRACT FROM AUTHOR]
Copyright of Chinese Journal of Polymer Science (Springer Science & Business Media B.V.) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Optimizing heavy-duty anticorrosive performances of coating films formed by acrylate-vinylidene chloride copolymer latexes through twice-painting technique.
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  Data: Twice-painting technique was adopted to prepare heavy-duty anticorrosive coating films formed by aqueous latexes of copolymers of vinylidene chloride (VDC) with an acrylate, namely methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA) or 2-ethylhexyl acrylate (EHA). Harsh salt-spray corrosion tests demonstrated that the optimized twice-painting technique was that the acidic latex solution was adjusted to pH 5-6 for the first painting, while it was utilized directly for the second painting. The test of 600 h of harsh salt-spray corrosion showed that MA-VDC85 coating could protect the steel excellently, whereas the other acrylate-VDC coatings with 75%-90% VDC content could not protect the steel so effectively. Further corrosion test showed that (1) MA-VDC85 coating protected steel from loss of metallic luster for at least 1000 h of salt-spray corrosion; (2) adhesion of MA-VDC85 coating to steel was excellent for at least 800 h of salt-spray corrosion, but became very poor after 1000 h. Differential scanning calorimetry, thermogravimetric analysis, X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy were used to evaluate the corroded MA-VDC85 film. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Chinese Journal of Polymer Science (Springer Science & Business Media B.V.) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s10118-015-1570-x
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        Text: English
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      – SubjectFull: Corrosion inhibitors
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      – SubjectFull: Surface coatings
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      – SubjectFull: Thin films
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      – SubjectFull: Acrylates
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      – SubjectFull: Dichloroethylene
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      – SubjectFull: Painting techniques
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      – TitleFull: Optimizing heavy-duty anticorrosive performances of coating films formed by acrylate-vinylidene chloride copolymer latexes through twice-painting technique.
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              Text: Jan2015
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              Y: 2015
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